A 1H and 13C NMR and UV study of the state of hydroxyacetone in aqueous solutions

被引:22
作者
Glushonok, GK [1 ]
Glushonok, TG [1 ]
Maslovskaya, LA [1 ]
Shadyro, OI [1 ]
机构
[1] Belarusian State Univ, Res Inst Physicochem Problems, Minsk 220050, BELARUS
关键词
D O I
10.1023/B:RUGC.0000007604.91106.60
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The state of hydroxyacetone in neutral aqueous solutions was studied by H-1 and C-13 NMR and UV spectroscopy. In the concentration range 0.1-1.41 M, 96-98% of hydroxyacetone exists in the carbonyl form. The content of the hydrated form of hydroxyacetone is 2-4%. No dimeric and polymeric species were detected.
引用
收藏
页码:1027 / 1031
页数:5
相关论文
共 27 条
[1]  
Balashov AL, 1998, ZH OBSHCH KHIM+, V68, P1152
[2]   KINETICS OF THE HYDRATION OF ACETALDEHYDE [J].
BELL, RP ;
RAND, MH ;
WYNNEJONES, KMA .
TRANSACTIONS OF THE FARADAY SOCIETY, 1956, 52 (08) :1093-1102
[3]   THE HYDRATION OF ACETALDEHYDE IN AQUEOUS SOLUTION [J].
BELL, RP ;
CLUNIE, JC .
TRANSACTIONS OF THE FARADAY SOCIETY, 1952, 48 (05) :439-442
[4]   THE KINETICS OF THE HYDRATION OF ACETALDEHYDE [J].
BELL, RP ;
DARWENT, BD .
TRANSACTIONS OF THE FARADAY SOCIETY, 1950, 46 (01) :34-41
[5]   HYDRATION EQUILIBRIA OF SOME ALDEHYDES AND KETONES [J].
BELL, RP ;
MCDOUGALL, AO .
TRANSACTIONS OF THE FARADAY SOCIETY, 1960, 56 (09) :1281-1285
[6]   NUCLEAR MAGNETIC RESONANCE SPECTRA OF GLYCOLALDEHYDE [J].
COLLINS, GCS ;
GEORGE, WO .
JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1971, (07) :1352-&
[7]   STRUCTURE OF DIHYDROXYACETONE IN SOLUTION [J].
DAVIS, L .
BIOORGANIC CHEMISTRY, 1973, 2 (03) :197-201
[8]  
GLUSHONOK GK, 1986, ZH FIZ KHIM+, V60, P2960
[9]  
GLUSHONOK GK, 1986, ZH FIZ KHIM+, V60, P2971
[10]  
GLUSHONOK GK, 1984, ZH FIZ KHIM+, V58, P111