ZnO nanocapsules for photocatalytic degradation of thionine

被引:43
作者
Khayyat, Suzan A. [2 ]
Akhtar, M. S. [3 ]
Umar, Ahmad [1 ,4 ]
机构
[1] Najran Univ, Dept Chem, Fac Sci & Arts, Najran 11001, Saudi Arabia
[2] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah, Saudi Arabia
[3] Chonbuk Natl Univ, New & Renewable Energy Mat Dev Ctr New REC, Chonju, South Korea
[4] Najran Univ, Promising Ctr Sensors & Elect Devices PCSED, Najran 11001, Saudi Arabia
关键词
ZnO nanocapsules; Thionine dye; Photocatalysts; Photodegradation; Illumination; VISIBLE-LIGHT ILLUMINATION; NANOSHEETS; NANORODS; DYES;
D O I
10.1016/j.matlet.2012.04.039
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This paper reports the successful synthesis of ZnO nanocapsules and their utilization as a photocatalyst for photocatalytic degradation of thionine. The nanocapsules were synthesized by facile hydrothermal process and characterized in detail in terms of their morphological, structural and optical properties. The detailed studies revealed that the synthesized nanocapsules possess well-crystalline and good optical properties. By utilizing the as-synthesized ZnO nanocapsules as a photocatalyst, significant photocatalytic degradation was observed towards thionine dye under light illumination. The considerable photo-degradation of thionine dye was due to the unique morphology and high surface area of synthesized ZnO nanocapsules which might import the effective electron/hole separation and might generate the large number of oxy-radicals. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:239 / 241
页数:3
相关论文
共 31 条
[1]  
Akhtar MS, 2010, J NANOENG NANOMANUF, V1, P71
[2]   Synthesis and photocatalytic activity of cobalt oxide doped ZnFe2O4-Fe2O3-ZnO mixed oxides [J].
Bai, Jiahai .
MATERIALS LETTERS, 2009, 63 (17) :1485-1488
[3]   Transition in the Optical Emission Polarization of ZnO Nanorods [J].
Baskoutas, Sotirios ;
Bester, Gabriel .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (32) :15862-15867
[4]   Conventional Optics from Unconventional Electronics in ZnO Quantum Dots [J].
Baskoutas, Sotirios ;
Bester, Gabriel .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (20) :9301-9307
[5]  
Chandrasekaran S, 2010, J NANOENG NANOMANUF, V1, P242
[6]   Production of Hydrogen by Partial Oxidation of Methanol Over ZnO-Promoted Copper Catalysts Supported on Rice Husk Ash [J].
Chen, Wun-Syong ;
Chang, Feg-Wen ;
Roselin, L. Selva ;
Ou, Ti-Cheng .
SCIENCE OF ADVANCED MATERIALS, 2012, 4 (01) :68-77
[7]   EFFECTS OF COLLOIDAL SIO2 AND CYCLODEXTRINS ON THE AGGREGATION OF DYES IN AQUEOUS-SOLUTIONS [J].
DAN, P ;
WILLNER, I ;
DIXIT, NS ;
MACKAY, RA .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1984, (03) :455-459
[8]   Fabrication of Highly Sensitive Non-Enzymatic Glucose Biosensor Based on ZnO Nanorods [J].
Dar, G. N. ;
Umar, Ahmad ;
Zaidi, Shabi Abbas ;
Baskoutas, S. ;
Kim, S. H. ;
Abaker, M. ;
Al-Hajry, A. ;
Al-Sayari, S. A. .
SCIENCE OF ADVANCED MATERIALS, 2011, 3 (06) :901-906
[9]   Unusual photoreactivity of zinc oxide irradiated by concentrated sunlight [J].
Dindar, B ;
Içli, S .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2001, 140 (03) :263-268
[10]  
He Z, 2011, J NANOENG NANOMANUF, V2, P17