Epoxide formation by indirect electroreductive coupling between aldehydes or ketones and activated gem-dichloro compounds

被引：17

作者：

Oudeyer, S ^{[1
]}

Léonel, E ^{[1
]}

Paugam, JP ^{[1
]}

Nédélec, JY ^{[1
]}

机构：

[1] Univ Paris 12, CNRS, LECSO, UMR 7582, F-94320 Thiais, France

来源：

SYNTHESIS-STUTTGART | 2004年 / 03期

关键词：

epoxides; coupling; aldehydes; ketones; condensation; reductions;

D O I：

10.1055/s-2004-815915

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Epoxides are prepared by indirect electroreductive coupling of carbonyl compounds (aldehydes or ketones) and activated gem-dichloro compounds. This process is more efficient with aryl ketones than with aryl aldehydes. Though yields are only moderate, this method offers the valuable advantage of avoiding the use of strong bases or peroxides.

引用

页码：389 / 400

页数：12

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