CF3S-platinum(II) complexes with fluorinated dithioethers.: Molecular structures of [Pt(SCF3)2(RfSCH2CH2SRf)] Rf = C6H4F-2 and C6H4F-3

被引：0

作者：

Cervantes, Ruy ^{[1
]}

Duran, Ubaldo ^{[1
]}

Bernes, Sylvain ^{[2
]}

Torrens, Hugo ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Fac Quim, Mexico City 04510, DF, Mexico

[2] Univ Autonoma Nuevo Leon, Fac Ciencias Quim, Nicolas De Los Garza, Nuevo Leon, Mexico

来源：

JOURNAL OF THE MEXICAN CHEMICAL SOCIETY | 2007年 / 51卷 / 01期

关键词：

fluorothiols; fluorothioetheres; platinum; VT-NMR; X-ray;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper describes the synthesis and characterization of the platinum(II) compounds cis-[Pt(SCF3)(2)(RfSCH2CH2SRf)] R-f = C6F5 1, C6HF4-4 2, C6H4F-2 3, C6H4F-3 4, C6H4F-4 5 and C6H4(CF3)(3) 6. Variable temperature F-19 NMR spectra of these complexes, show the presence and interconvertion of syn and anti isomers, consistent with a fast flipping of the metalocycle ring and a slow inversion of configuration at the dithioether sulfur atoms. The molecular and crystalline structures of the compounds [Pt(SCF3)(2)(2-C6H4 FSCH2 CH2SC6H4F-2)](3) and [Pt(SCF3)(2)(3-C6H4FSCH2CH2SC6H4F-3)] 4, solved by X-ray diffraction are also described.

引用

页码：20 / 26

页数：7

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