Polyoxyethylene alkyl ether carboxylic acids: An overview of a neglected class of surfactants with multiresponsive properties

被引:44
作者
Chiappisi, Leonardo [1 ,2 ]
机构
[1] Tech Univ Berlin, Stranski Lab Phys Chem & Theoret Chem, Inst Chem, Str 17 Juni 124,Sekr TC7, D-10623 Berlin, Germany
[2] Inst Max von Laue Paul Langevin, Large Scale Struct Grp, 71 Ave Martyrs, F-38042 Grenoble 9, France
关键词
Polyoxyethylene alkyl ether carboxylic acids; Surfactant science; Self-assembly; MICELLAR-ENHANCED ULTRAFILTRATION; ANGLE NEUTRON-SCATTERING; NONIONIC SURFACTANT; PHASE-BEHAVIOR; CLOUD-POINT; AQUEOUS-SOLUTIONS; FATTY-ACIDS; ANIONIC SURFACTANT; MAGNETIC NANOPARTICLES; SELECTIVE OXIDATION;
D O I
10.1016/j.cis.2017.10.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, an overview on aqueous solutions of polyoxyethylene alkyl ether carboxylic acids is given. Unique properties arise from the combination of the nonionic, temperature-responsive polyoxyethylene block with the weakly ionic, pH-responsive carboxylic acid termination in a single surfactant headgroup. Accordingly, this class of surfactant finds broad application across very different sectors. Despite their large use on an industrial and a technical scale, the literature lacks a systematic and detailed characterization of their physico-chemical properties which is provided herein. In addition, a comprehensive overview is given of their self-assembly and interfacial behavior, of their use as colloidal building blocks and for large-scale applications. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:79 / 94
页数:16
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