Three-dimensional lanthanide thiophenedicarboxylate framework with an unprecedented (4,5)-connected topology

被引：123
|
作者：
Wang, Jin-Gen [1 ]
Huang, Chang-Cang [1 ]
Huang, Xi-He [1 ]
Liu, Dong-Sheng [1 ,2 ]
机构：
[1] Fuzhou Univ, Dept Chem, Fuzhou 350002, Peoples R China
[2] Jinggangshan Univ, Dept Chem, Jian 343009, Jiangxi, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2008年 / 8卷 / 03期
关键词：
D O I：
10.1021/cg7011342
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three novel three-dimensional metal-organic frameworks [Ln(2)(tdc)(3)(H2O)(4)](n), Ln = Dy(1), Ho(2), Er(3) (H(2)tdc = thiophene-2,5-dicarboxylic acid) have been synthesized and characterized by single crystal X-ray diffraction (XRD), powder XRD and IR spectra. X-ray crystallography reveals that the three complexes are isostructural and exhibit an unprecedented (4,5)-connected (4(2)center dot 6(4))(4(2)center dot 6(7)center dot 8) topology, in which the lanthanide ions act as unusual 5-connected nodes. The thermal stability and UV-vis absorption spectra of the title complexes have also been studied.
引用
收藏
页码：795 / 798
页数：4
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