Observation of a ferric hydroperoxide complex during the non-heme iron catalysed oxidation of alkenes and alkanes by O2

被引：23
作者：
He, Yu [1 ]
Goldsmith, Christian R. [1 ]
机构：
[1] Auburn Univ, Dept Chem & Biochem, Auburn, AL 36849 USA
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 85期
关键词：
DIOXYGEN ACTIVATION; HYDROGEN PEROXIDE; FE(II) COMPLEXES; OXYGEN; LIGANDS; INTERMEDIATE; HYDROCARBONS; REACTIVITY; BLEOMYCIN; CHEMISTRY;
D O I：
10.1039/c2cc34634f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A non-heme iron complex catalyses the oxidation of allylic, benzylic, and aliphatic C-H bonds by O-2. During this reactivity, a ferric hydroperoxide species is observed. The kinetic analysis of this complex's formation may suggest a ferric superoxo species as the initial metal-based oxidant.
引用
收藏
页码：10532 / 10534
页数：3
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