Extraction of valuable metals from manganese-silver ore

被引:40
作者
Tian, Qing-hua [1 ]
Jiao, Cui-yan [1 ]
Guo, Xue-yi [1 ]
机构
[1] Cent S Univ, Sch Met Sci & Engn, Changsha 410083, Peoples R China
关键词
Manganese-silver ore; Reductive leaching; Complexation leaching; SULFURIC-ACID; CYANIDATION; KINETICS; GOLD; FERRICYANIDE; DISSOLUTION; OXIDATION; DIOXIDE;
D O I
10.1016/j.hydromet.2012.03.005
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
A combined novel process was developed to extract valuable metals from manganese-silver ore. The preferential dissolution of manganese from the primary materials was achieved through reductive leaching in dilute sulfuric acid medium with sodium sulfite as the reductant. Silver, which was enriched in the reductive leaching residue, was leached by complexation dissolution with hydrochloric acid and calcium chloride solution. Effects of process parameters on manganese extraction in the reductive leaching process were investigated, including the average particle size, the amount of sodium sulfite addition, sulfuric acid addition. liquid/solid ratio, leaching temperature and time. As for the silver extraction, the effects of Cl- concentration, hydrochloric acid addition, leaching temperature and time were also addressed. The results suggested that the extraction of manganese and silver could reach 99% and 92% respectively at the optimum conditions, while the high silica-containing product was obtained as the final residue. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:8 / 15
页数:8
相关论文
共 25 条
[1]   PERCOLATION LEACHING OF MANGANESE ORE BY AQUEOUS SULFUR-DIOXIDE [J].
ABBRUZZESE, C .
HYDROMETALLURGY, 1990, 25 (01) :85-97
[2]   SILVER EXTRACTION FROM A REFRACTORY TYPE ORE BY THIOUREA LEACHING [J].
ACMA, E ;
ARSLAN, F ;
WUTH, W .
HYDROMETALLURGY, 1993, 34 (02) :263-274
[3]   Reductive dissolution of manganese ore in sulfuric acid in the presence of iron metal [J].
Bafghi, Mohammad Sh. ;
Zakeri, Alireza ;
Ghasemi, Zahra ;
Adeli, Mandana .
HYDROMETALLURGY, 2008, 90 (2-4) :207-212
[4]   Thiourea leaching of silver from mechanically activated tetrahedrite [J].
Balaz, P ;
Ficeriova, J ;
Sepelak, V ;
Kammel, R .
HYDROMETALLURGY, 1996, 43 (1-3) :367-377
[5]   GOLD AND SILVER EXTRACTION FROM HELLYER LEAD-ZINC FLOTATION MIDDLINGS USING PRESSURE OXIDATION AND THIOUREA LEACHING [J].
BRUCKARD, WJ ;
SPARROW, GJ ;
WOODCOCK, JT .
HYDROMETALLURGY, 1993, 33 (1-2) :17-41
[6]  
Dean J A, 1998, LANGES HDB CHEM
[7]   Reductive acid leaching of manganese dioxide with glucose: Identification of oxidation derivatives of glucose [J].
Furlani, G ;
Pagnanelli, F ;
Toro, L .
HYDROMETALLURGY, 2006, 81 (3-4) :234-240
[8]   SELECTIVE AND NON-SELECTIVE BIOLEACHING OF MANGANESE FROM A MANGANESE-CONTAINING SILVER ORE [J].
GUPTA, A ;
EHRLICH, HL .
JOURNAL OF BIOTECHNOLOGY, 1989, 9 (04) :287-304
[9]   Simultaneous leaching of manganese and silver from manganese-silver ores at room temperature [J].
Jiang, T ;
Yang, YB ;
Huang, ZC ;
Qiu, GZ .
HYDROMETALLURGY, 2003, 69 (1-3) :177-186
[10]  
Jiang T, 1996, CHINAS MANGANESE IND, V11, P73