Parallel advances in improving mechanical properties and accelerating degradation to polylactic acid

被引:28
作者
Wan Lu [1 ]
Zhou Shuai [1 ]
Zhang Yanhua [1 ]
机构
[1] Northeast Forestry Univ, Coll Mat Sci & Engn, Harbin 150040, Heilongjiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Mechanical properties; Polylactic acid; Hydrolysis; Composite material; WOOD FLOUR; HYDROLYTIC DEGRADATION; POLY(LACTIC ACID); CRYSTALLIZATION BEHAVIORS; POLY(METHYL METHACRYLATE); THERMAL-PROPERTIES; PARTICLE-SIZE; FIBER SIZE; PLA; SURFACE;
D O I
10.1016/j.ijbiomac.2018.12.148
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Going up further on the basis of excellent mechanical properties and solving the long-standing shortcoming of the slow degradation rate were developed in parallel for polylactic acid (PLA). The polylactic acid/wood flour/polymethylmethacrylate (PLA/WF/PMMA) composites were prepared by melt blending used PIA as matrix, WF of diverse particle size with PMMA at 8:2 mass ratio totally filled with 20 wt%. The PLA/WF/PMMA composites were studied by means of Fourier transform infrared spectroscopy (FTIR), differential scanning calorimeter (DSC), melting index test, and universal mechanical properties test. The result shows that WF of 150 pm < particle size < 180 mu m executed the optimal improvement to mechanical properties of PLA/WF/PMMA. Tensile strength, flexural modulus and Young's modulus of PLA/WF/PMMA (150-180 mu m) were enhanced 10.02%, 37.21% and 32.80% in relation to neat PIA, respectively. Hydrophilic contact angle test, water absorption measurement and hydrolysis assessment were performed to the hydrolysis degradation performance of materials. Furthermore, PMMA and WF cooperatively assisted in enormously accelerating hydrolysis of PLA, eventually having a good performance. Improving mechanical properties and accelerating degradation at the same time are of great significance for expanding the application of PLA. (C) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码:1093 / 1102
页数:10
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