Surface and bulk mobilities of oligothiophene single crystals

被引:42
作者
Schön, JH [1 ]
Kloc, C [1 ]
Laudise, RA [1 ]
Batlogg, B [1 ]
机构
[1] AT&T Bell Labs, Lucent Technol, Murray Hill, NJ 07974 USA
关键词
D O I
10.1063/1.122828
中图分类号
O59 [应用物理学];
学科分类号
摘要
High-quality single crystals of alpha-quaterthiophene (alpha-4T) and alpha-hexathiophene (alpha-6T) were investigated to compare intrinsic bulk and surface electrical properties. The bulk properties of these organic p-type semiconductors are derived from extended current-voltage characteristics and the surface properties from single crystal field-effect transistor measurements. Most significantly, charge carrier mobilities as high as 0.5 cm(2)/V s are observed in alpha-6T both in the bulk and at the surface. The high quality and purity of the crystals are evident from the low trap densities (<10(15) cm(-3)) and the even lower dopant concentrations (2 x 10(13) for alpha-4T and 7 x 10(10) cm(-3) for alpha-6T). These intrinsically high performance figures, together with the ease of processing, make these oligothiophenes attractive materials for "plastic electronic'' devices. (C) 1998 American Institute of Physics. [S0003-6951(98)02850-2].
引用
收藏
页码:3574 / 3576
页数:3
相关论文
共 12 条
[1]   FIELD-EFFECT TRANSISTORS USING ALKYL SUBSTITUTED OLIGOTHIOPHENES [J].
AKIMICHI, H ;
WARAGAI, K ;
HOTTA, S ;
KANO, H ;
SAKAKI, H .
APPLIED PHYSICS LETTERS, 1991, 58 (14) :1500-1502
[2]   Molecular beam deposited thin films of pentacene for organic field effect transistor applications [J].
Dimitrakopoulos, CD ;
Brown, AR ;
Pomp, A .
JOURNAL OF APPLIED PHYSICS, 1996, 80 (04) :2501-2508
[3]   ORGANIC TRANSISTORS - 2-DIMENSIONAL TRANSPORT AND IMPROVED ELECTRICAL CHARACTERISTICS [J].
DODABALAPUR, A ;
TORSI, L ;
KATZ, HE .
SCIENCE, 1995, 268 (5208) :270-271
[4]   Pentacene organic thin-film transistors - Molecular ordering and mobility [J].
Gundlach, DJ ;
Lin, YY ;
Jackson, TN ;
Nelson, SF ;
Schlom, DG .
IEEE ELECTRON DEVICE LETTERS, 1997, 18 (03) :87-89
[5]  
HOROWITZ G, 1995, J PHYS III, V5, P355, DOI 10.1051/jp3:1995132
[6]   Field-effect transistor made with a sexithiophene single crystal [J].
Horowitz, G ;
Garnier, F ;
Yassar, A ;
Hajlaoui, R ;
Kouki, F .
ADVANCED MATERIALS, 1996, 8 (01) :52-&
[7]   A FIELD-EFFECT TRANSISTOR BASED ON CONJUGATED ALPHA-SEXITHIENYL [J].
HOROWITZ, G ;
FICHOU, D ;
PENG, XZ ;
XU, ZG ;
GARNIER, F .
SOLID STATE COMMUNICATIONS, 1989, 72 (04) :381-384
[8]  
Hwang W., 1981, Electrical transport in solids
[9]   Physical vapor growth of centimeter-sized crystals of α-hexathiophene [J].
Kloc, C ;
Simpkins, PG ;
Siegrist, T ;
Laudise, RA .
JOURNAL OF CRYSTAL GROWTH, 1997, 182 (3-4) :416-427
[10]   Pentacene-based organic thin-film transistors [J].
Lin, YY ;
Gundlach, DJ ;
Nelson, SF ;
Jackson, TN .
IEEE TRANSACTIONS ON ELECTRON DEVICES, 1997, 44 (08) :1325-1331