Tailoring microporosity in covalent organic frameworks

被引:399
作者
Tilford, R. William [1 ]
Mugavero, Sam J., III [1 ]
Pellechia, Perry J. [1 ]
Lavigne, John J. [1 ]
机构
[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA
关键词
D O I
10.1002/adma.200800030
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The microporosity of covalent organic frameworks (COFs) is tailored using a facile synthetic approach that introduces alkyl functionalities into the pore and generates networks with pore diameters between 1-2 nm. The added substituents significantly alter the host-guest properties of the resulting materials.
引用
收藏
页码:2741 / +
页数:7
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共 60 条
[1]   Selective adsorption and separation of xylene isomers and ethylbenzene with the microporous vanadium(IV) terephthalate MIL-47 [J].
Alaerts, Luc ;
Kirschhock, Christine E. A. ;
Maes, Michael ;
van der Veen, Monique A. ;
Finsy, Vincent ;
Depla, Anouschka ;
Martens, Johan A. ;
Baron, Gino V. ;
Jacobs, Pierre A. ;
Denayer, Joeri E. M. ;
De Vos, Dirk E. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (23) :4293-4297
[2]   FT-NMR INVESTIGATION OF C-13-B-11 COUPLING [J].
AXELSON, DE ;
OLIVER, AJ ;
HOLLOWAY, CE .
ORGANIC MAGNETIC RESONANCE, 1973, 5 (05) :255-256
[3]   Tailored porous materials [J].
Barton, TJ ;
Bull, LM ;
Klemperer, WG ;
Loy, DA ;
McEnaney, B ;
Misono, M ;
Monson, PA ;
Pez, G ;
Scherer, GW ;
Vartuli, JC ;
Yaghi, OM .
CHEMISTRY OF MATERIALS, 1999, 11 (10) :2633-2656
[4]   Crystal engineering and organometallic architecture [J].
Braga, D ;
Grepioni, F ;
Desiraju, GR .
CHEMICAL REVIEWS, 1998, 98 (04) :1375-1405
[5]   Developments in inorganic crystal engineering [J].
Brammer, L .
CHEMICAL SOCIETY REVIEWS, 2004, 33 (08) :476-489
[6]   Structure and catalytic properties of Pt-modified hyper-cross-linked polystyrene exhibiting hierarchical porosity [J].
Bronstein, LM ;
Goerigk, G ;
Kostylev, M ;
Pink, M ;
Khotina, IA ;
Valetsky, PM ;
Matveeva, VG ;
Sulman, EM ;
Sulman, MG ;
Bykov, AV ;
Lakina, NV ;
Spontak, RJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (47) :18234-18242
[7]   The potential of organic polymer-based hydrogen storage materials [J].
Budd, Peter M. ;
Butler, Anna ;
Selbie, James ;
Mahmood, Khalid ;
McKeown, Neil B. ;
Ghanem, Bader ;
Msayib, Kadhum ;
Book, David ;
Walton, Allan .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (15) :1802-1808
[8]   Free volume and intrinsic microporosity in polymers [J].
Budd, PM ;
McKeown, NB ;
Fritsch, D .
JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (20) :1977-1986
[9]   Solution-processed, organophilic membrane derived from a polymer of intrinsic microporosity [J].
Budd, PM ;
Elabas, ES ;
Ghanem, BS ;
Makhseed, S ;
McKeown, NB ;
Msayib, KJ ;
Tattershall, CE ;
Wang, D .
ADVANCED MATERIALS, 2004, 16 (05) :456-+
[10]   Reticular synthesis of microporous and mesoporous 2D covalent organic frameworks [J].
Cote, Adrien P. ;
El-Kaderi, Hani M. ;
Furukawa, Hiroyasu ;
Hunt, Joseph R. ;
Yaghi, Omar M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (43) :12914-+