Performance Evolution of Alkylation Graphene Oxide Reinforcing High-Density Polyethylene

被引:17
作者
Gao, Wensheng [1 ]
Lu, Yue [1 ]
Chao, Yuanzhi [1 ]
Ma, Yu [1 ]
Zhu, Bochao [2 ]
Jia, Junji [2 ]
Huang, Anping [2 ]
Xie, Kefeng [2 ]
Li, Jiangong [1 ]
Bai, Yongxiao
机构
[1] Lanzhou Univ, Inst Mat Sci & Engn, MOE Key Lab Magnetism & Magnet Mat, Lanzhou 730000, Gansu, Peoples R China
[2] Petro China, Lanzhou Petrochem Res Ctr, Lanzhou 730000, Gansu, Peoples R China
关键词
ISOTACTIC-POLYPROPYLENE NANOCOMPOSITES; FUNCTIONALIZED GRAPHENE; MECHANICAL-PROPERTIES; THERMAL-PROPERTIES; REACTIVE COMPATIBILIZATION; COMPOSITES; CONDUCTIVITY; EXFOLIATION; CRYSTALLIZATION; POLYMER;
D O I
10.1021/acs.jpcc.7b06142
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Alkylated graphene oxide (MGO) was rapidly prepared by a reverse extraction technology in aqueous solution using amphoteric surfactants (LAO). The MGO has an excellent lipophilicity and stability in the air atmosphere. After being incorporated in high-density polyethylene (HDPE) by solution compounding, the HDPE/MGO composites exhibited an obvious enhancement in comprehensive properties of composites, relying on the uniform dispersion and the strong interfacial interaction between MGO and HDPE. The typical -and abnormal behaviors of the HDPE/MGO in Mechanical and physical properties are systematically analyzed and, discussed. MOreciVer, it is found that the critical intensity ratio of ICH2/IC=c/c-c in Raman spectrum corresponding to the electric percolation threshold of HDPE/MGO is about 1, which is still well established in PP/MGO composites.
引用
收藏
页码:21685 / 21694
页数:10
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