Synthesis of the β-hydroxydopa-γ-hydroxy-δ-sulfinylnorvaline component of ustiloxins A and B

被引：6

作者：

Hunter, L

Malcolm, DMA

Hutton, CA ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

[2] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2005年 / 3卷 / 05期

关键词：

D O I：

10.1039/b418876d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The dopa-sulfinylnorvaline component of ustiloxins A and B has been prepared using an Evans salen-Al-catalysed aldol reaction with a 6-mercaptoisovanillin derivative, followed by incorporation of the norvaline group and asymmetric oxidation of the resulting sulfide to give the corresponding sulfoxide.

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页码：732 / 734

页数：3

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