Template synthesis of a rare 14-membered macrocyclic complex using cadmium(II) ion as a collector

被引：0

作者：

Dorjani, Sima ^{[1
]}

Mardani, Zahra ^{[1
]}

Moeini, Keyvan ^{[2
]}

Carpenter-Warren, Cameron ^{[3
]}

机构：

[1] Urmia Univ, Fac Chem, Inorgan Chem Dept, Orumiyeh 5756151818, Iran

[2] Payame Noor Univ, Chem Dept, Tehran 193954697, Iran

[3] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2022年 / 102卷 / 5-6期

关键词：

14-Membered macrocycle; Cadmium; Diazacyclam; CSD; DFT; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURE; COORDINATION; LIGAND; POLYAZA; CD(II); ZN(II); CYCLAM; NI(II);

D O I：

10.1007/s10847-022-01136-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this work, a new macrocyclic cadmium complex, [Cd(ACE)I](2)[CdI4] (1); ACE: 1,3,6,10,12,15-hexaazatricyclo[13.3.1.1(6,10)]eicosane, was prepared by template method and characterized by elemental analysis, FT-IR spectroscopy and single-crystal X-ray diffraction. Structural analysis of the complex 1 revealed an ionic complex containing two cadmium atoms with tetrahedral (in anionic portion) and square-pyramidal (in cationic portion) geometries. Using the DFT calculations, thermodynamic stability of the first-row and group 12 metal complexes containing ACE ligand was investigated and then validated by comparing with the CSD analogues. Charge distribution pattern of ACE ligand was compared with cationic unit of 1 by NBO analysis to study of the charge variation of ligand after complexation. [GRAPHICS] .

引用

页码：523 / 531

页数：9

共 50 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE
ADDISON, AW
RAO, TN
REEDIJK, J
VANRIJN, J
VERSCHOOR, GC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07): : 1349 - 1356
[2] Polyaza and azaoxa macrocyclic receptors functionalised with fluorescent subunits;: Hg2+ selective signalling
Al Shihadeh, Y
Benito, A
Lloris, JM
Martínez-Máñez, R
Pardo, T
Soto, J
Marcos, MD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (07): : 1199 - 1205
[3] The Cambridge Structural Database: a quarter of a million crystal structures and rising
Allen, FH
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1): : 380 - 388
[4] SOLVENT-EXTRACTION OF RADIUM WITH CROWN-ETHER CARBOXYLIC-ACIDS
BEKLEMISHEV, MK
ELSHANI, S
WAI, CM
[J]. ANALYTICAL CHEMISTRY, 1994, 66 (20) : 3521 - 3524
[5] Evaluation of crystallographic data with the program DIAMOND
Bergerhoff, G
Berndt, M
Brandenburg, K
[J]. JOURNAL OF RESEARCH OF THE NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY, 1996, 101 (03) : 221 - 225
[6] Burnett M.N., 1996, ORTEP-III: Oak Ridge Thermal Ellipsoid Plot Program for Crystal Structure Illustrations, DOI DOI 10.1021/ol1009224
[7] Variation in the coordination mode of arenedisulfonates: Syntheses and structural characterization of mononuclear and dinuclear cadmium(II) arenedisulfonate complexes with two- to zero-dimensional architectures
Chen, CH
Cai, JW
Liao, CZ
Feng, XL
Chen, XM
Ng, SW
[J]. INORGANIC CHEMISTRY, 2002, 41 (19) : 4967 - 4974
[8] Choi KY, 2001, MAIN GROUP MET CHEM, V24, P119
[9] A novel dodecanuclear cadmium(II) macrocycle with a 3D framework: synthesis, structure and properties
Chu, Wenjuan
Wu, Benlai
Tang, Mingsheng
Fan, Yaoting
Hou, Hongwei
[J]. CRYSTENGCOMM, 2012, 14 (13) : 4414 - 4419
[10] Constable E.D., 1995, Metals and Ligand Reactivity

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