Inhibition effect of {cationic surfactant-ascorbic acid} premicellar aggregation on the rate of hexacyanoferrate(III) oxidation of ascorbic acid: A kinetic study

被引：5

作者：

Shukla, Ratna ^{[1
]}

Kambo, Neelu ^{[1
]}

Upadhyay, Santosh K. ^{[1
]}

机构：

[1] Harcourt Butler Technol Inst, Dept Chem, Kanpur 208002, Uttar Pradesh, India

来源：

JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY | 2008年 / 29卷 / 06期

关键词：

ascorbic acid; cetyltrimethylammonium bromide; hexacynoferrate (III); kinetics of oxidation;

D O I：

10.1080/01932690701783580

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics of oxidation of ascorbic acid by acidic hexacyanoferrate(HI) have been investigated in presence of cationic surfactant viz. cetyltrimethylammonium bromide (CTAB). An inhibition effect of CTAB (below its critical micelle concentration) on the rate of oxidation has been observed. The spectrophotometric and kinetic data support a 1:1 premicellar association between substrate and surfactant. A mechanism has been proposed and a rate law consistent with kinetic results has been derived.

引用

页码：905 / 909

页数：5

共 50 条

[1] Inhibition effect of Brij-35 on the rate of oxidation of ascorbic acid by hexacyanoferrate(III) in acidic medium: A kinetic study
Shukla, Ratna
Upadhyay, Santosh K.
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2007, 46 (07): : 1116 - 1120
[2] Ionic strength effect on the rate of reduction of hexacyanoferrate(III) by ascorbic acid - A flow injection kinetic experiment
Nobrega, JA
Rocha, FRP
JOURNAL OF CHEMICAL EDUCATION, 1997, 74 (05) : 560 - 562
[3] Ionic strength effect on the rate of reduction of hexacyanoferrate(III) by ascorbic acid: A flow injection kinetic experiment
Department of Chemistry, Fed. University of São Carlos, Caixa Postal 676, 13.560-270, São Carlos, SP, Brazil
J Chem Educ, 5 (560-562):
[4] Kinetic study of the hexacyanoferrate (III) oxidation of dihydroxyfumaric acid in acid
Garcia, B.
Ruiz, R.
Leal, J. M.
JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 112 (22): : 4921 - 4928
[5] Effect of cationic surfactant on Ru(III) catalyzed L-glutamic acid oxidation by hexacyanoferrate(III)
Srivastava, Abhishek
Goswami, Madhav Krishna
Dohare, Rajeev Kumar
Srivastava, Neetu
Srivastava, Krishna
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2023, 55 (08) : 431 - 440
[6] Atmospheric and electrochemical oxidation of ascorbic acid in anionic, nonionic and cationic surfactant systems
Szymula, M
Narkiewicz-Michalek, J
COLLOID AND POLYMER SCIENCE, 2003, 281 (12) : 1142 - 1148
[7] Atmospheric and electrochemical oxidation of ascorbic acid in anionic, nonionic and cationic surfactant systems
Marta Szymula
Jolanta Narkiewicz-Michałek
Colloid and Polymer Science, 2003, 281 : 1142 - 1148
[8] Inhibition effect of {surfactant-substrate} aggregation on the rate of oxidation of reducing sugars by alkaline hexacyanoferrate(III)
Shukla, Ratna
Upadhyay, Santosh K.
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2007, 39 (11) : 595 - 604
[9] OXIDATION MECHANISMS OF L-ASCORBIC-ACID BY HEXACYANOFERRATE(III) IN STRONGLY ACIDIC MEDIA
MARTINEZ, P
ZULUAGA, J
RODRIGUEZ, AF
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-LEIPZIG, 1990, 271 (03): : 597 - 601
[10] SPECTROPHOTOMETRIC DETERMINATION OF ASCORBIC-ACID WITH POTASSIUM HEXACYANOFERRATE(III)
BURGER, N
KARASGAS, V
TALANTA, 1973, 20 (08) : 782 - 785

← 1 2 3 4 5 →