Group 4 metal compounds incorporating the amide ligand, [N(SiMe2{C6H4-2-OMe})2]-

被引：2

作者：

Evans, Lloyd T. J. ^{[1
]}

Farnaby, Joy H. ^{[1
]}

Coles, Martyn P. ^{[1
]}

Cloke, F. Geoffrey N. ^{[1
]}

Hitchcock, Peter B. ^{[1
]}

机构：

[1] Univ Sussex, Dept Chem, Brighton BN1 9QJ, E Sussex, England

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 19期

关键词：

OLEFIN POLYMERIZATION CATALYSTS; RAY CRYSTAL-STRUCTURE; ETHYLENE POLYMERIZATION; DIAMIDO LIGAND; ZIRCONIUM COMPLEXES; MOLECULAR-STRUCTURES; TITANIUM; DERIVATIVES; CONTAIN; LITHIUM;

D O I：

10.1039/c5dt00684h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The anisole-substituted silyl-amide anion, [N(SiMe2{C6H4-2-OMe})(2)](-) (L), has been used as a pincer-type ligand in coordination chemistry. X-ray diffraction data for the lithium salt shows a trimetallic structure consisting of two equivalents of Li(L) that sequester a molecule of LiCl. The potassium salt K(L) is dimeric in the solid-state with bridging amide ligands. Each structure shows chelation of both O-donor groups to the electropositive metal. In contrast, the titanium compound Ti(L)Cl-3 is four-coordinate with a monodentate amide. The zirconium compound Zr(L)(2)Cl-2 is monometallic with a six-coordinate metal and two N,O-bidentate amides.

引用

页码：8950 / 8958

页数：9

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