Nickel-catalysed synthesis of tetrasubstituted vinyl sulfides from thiocarbamates and internal alkynes

被引：30
|
作者：
Inami, Tasuku [1 ]
Kurahashi, Takuya [1 ,2 ]
Matsubara, Seijiro [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Nishikyo Ku, Kyoto 6158510, Japan
[2] JST, ACT C, Kawaguchi, Saitama 3320012, Japan
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 07期
基金：
日本学术振兴会;
关键词：
C-S BOND; TERMINAL ALKYNES; STEREOSELECTIVE-SYNTHESIS; AROMATIC THIOLS; REGIOSELECTIVE ADDITION; CONVENIENT SYNTHESIS; 1ST EXAMPLE; PALLADIUM; HYDROTHIOLATION; EFFICIENT;
D O I：
10.1039/c4cc09123j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The thiocarbamoylation of internal alkynes to produce tetrasubstituted beta-aminocarbonyl vinyl sulfides was demonstrated using a nickel catalyst. This reaction was successful with a wide variety of substituents, and gave the syn-adducts exclusively.
引用
收藏
页码：1285 / 1288
页数：4
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