Combined Magnetic Susceptibility Measurements and 57Fe Mossbauer Spectroscopy on a Ferromagnetic {Fe4IIIDy4} Ring

被引:117
作者
Schray, Dirk [1 ]
Abbas, Ghulam [1 ]
Lan, Yanhua [1 ]
Mereacre, Valeriu [1 ]
Sundt, Alexander [3 ]
Dreiser, Jan [3 ]
Waldmann, Oliver [3 ]
Kostakis, George E. [2 ]
Anson, Christopher E. [1 ]
Powell, Annie K. [1 ]
机构
[1] Karlsruhe Inst Technol, Inst Inorgan Chem, D-76128 Karlsruhe, Germany
[2] Karlsruhe Inst Technol, Inst Nanotechnol, D-76021 Karlsruhe, Germany
[3] Univ Freiburg, Inst Phys, D-79104 Freiburg, Germany
关键词
iron; lanthanides; magnetic properties; Mossbauer spectroscopy; single-molecule magnets;
D O I
10.1002/anie.201001110
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Ferromagnetic interactions in an Fe4Dy 4 single-molecule magnet were studied using a combination of magnetic susceptibility measurements (see diagram; inset: cluster core) and 57Fe Mössbauer spectroscopy. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5185 / 5188
页数:4
相关论文
共 10 条
  • [1] Magnetic and 57Fe Mossbauer Study of the Single Molecule Magnet Behavior of a Dy3Fe7 Coordination Cluster
    Abbas, Ghulam
    Lan, Yanhua
    Mereacre, Valeriu
    Wernsdorfer, Wolfgang
    Clerac, Rodolphe
    Buth, Gernot
    Sougrati, Moulay T.
    Grandjean, Fernande
    Long, Gary J.
    Anson, Christopher E.
    Powell, Annie K.
    [J]. INORGANIC CHEMISTRY, 2009, 48 (19) : 9345 - 9355
  • [2] Probing Lanthanide Anisotropy in Fe-Ln Aggregates by Using Magnetic Susceptibility Measurements and 57Fe Mossbauer Spectroscopy
    Akhtar, Muhammad Nadeem
    Mereacre, Valeriu
    Novitchi, Ghenadie
    Tuchagues, Jean-Pierre
    Anson, Christopher E.
    Powell, Annie K.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (30) : 7278 - 7282
  • [3] Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals
    Benelli, C
    Gatteschi, D
    [J]. CHEMICAL REVIEWS, 2002, 102 (06) : 2369 - 2387
  • [4] MOLECULAR MAGNETISM - A BASIS FOR NEW MATERIALS
    GATTESCHI, D
    [J]. ADVANCED MATERIALS, 1994, 6 (09) : 635 - 645
  • [5] DINUCLEAR COMPLEXES WITH PREDICTABLE MAGNETIC-PROPERTIES
    KAHN, O
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (10): : 834 - 850
  • [6] Kahn O., 1985, Angew. Chem, V97, P837
  • [7] Kahn O., 1993, MOL MAGNETISM, P3
  • [8] LONG GJ, 1991, NATO ADV SCI I C-MAT, V331, P355
  • [9] Strategies towards single molecule magnets based on lanthanide ions
    Sessoli, Roberta
    Powell, Annie K.
    [J]. COORDINATION CHEMISTRY REVIEWS, 2009, 253 (19-20) : 2328 - 2341
  • [10] Sheldrick G. M., 2003, SHELXTL 6 12