H2O2/Phosphonium Ionic Liquid: An Efficient and Simple Approach for Benzyl Halides Oxidation

被引:0
|
作者
Dake, Satish A. [2 ]
Kulkarni, Ravibhushan S. [2 ]
Rode, Ambadas B. [2 ]
Shinde, Pravin S. [2 ]
Ghumbre, Sushil K. [2 ]
Magar, Rupali L. [2 ]
Pawar, Rajendra P. [1 ]
机构
[1] Deogiri Coll, Dept Chem, Aurangabad 431005, Maharashtra, India
[2] Dnyanopasak Coll, Organ Chem Synth Lab, Parbhani 431401, Maharashtra, India
关键词
Benzyl halides; carbonyl compounds; aq. hydrogen peroxide (30%); ionic liquids; BAEYER-VILLIGER OXIDATION; O-IODOXYBENZOIC ACID; IODINE(V) REAGENTS; ORGANIC-SYNTHESIS; KETONES; IBX; ALCOHOLS; WATER;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An efficient oxidation of benzyl halide has been done using aqueous hydrogen peroxide (30%) in trihexyl(tetradecyl)phosphonium-tetrafluroborate ionic liquid the protocol is simple mild offering excellent yield of product.
引用
收藏
页码:491 / 494
页数:4
相关论文
共 50 条
  • [1] Efficient and convenient oxidation of organic halides to carbonyl compounds by H2O2 in ethanol
    Tang, Jingting
    Zhu, Jinlong
    Shen, Zongxuan
    Zhang, Yawen
    TETRAHEDRON LETTERS, 2007, 48 (11) : 1919 - 1921
  • [2] Solvent-free oxidation of toluene in an ionic liquid with H2O2 as oxidant
    Lu, Bin
    Cai, Na
    Sun, Jia
    Wang, Xin
    Li, Xin
    Zhao, Jingxiang
    Cai, Qinghai
    CHEMICAL ENGINEERING JOURNAL, 2013, 225 : 266 - 270
  • [3] Phosphonium Ionic Liquid: A Novel Catalyst for Benzyl Halide Oxidation
    Dake, Satish A.
    Kulkarni, Ravibhushan S.
    Kadam, Vijay N.
    Modani, Sandesh S.
    Bhale, Jayant J.
    Tathe, Sumangala B.
    Pawar, Rajendra P.
    SYNTHETIC COMMUNICATIONS, 2009, 39 (21) : 3898 - 3904
  • [4] Simple soluble Bi(III) salts as efficient catalysts for the oxidation of alkanes with H2O2
    Rocha, Bruno G. M.
    Kuznetsov, Maxim L.
    Kozlov, Yuriy N.
    Pombeiro, Armando J. L.
    Shul'pin, Georgiy B.
    CATALYSIS SCIENCE & TECHNOLOGY, 2015, 5 (04) : 2174 - 2187
  • [5] Mesoporous Polyoxometalate-Based Ionic Hybrid As a Triphasic Catalyst for Oxidation of Benzyl Alcohol with H2O2 on Water
    Chen, Guojian
    Zhou, Yu
    Long, Zhouyang
    Wang, Xiaochen
    Li, Jing
    Wang, Jun
    ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (06) : 4438 - 4446
  • [6] Iron-chloride ionic liquid immobilized on SBA-15 for solvent-free oxidation of benzyl alcohol to benzaldehyde with H2O2
    Cang, Ruibai
    Lu, Bin
    Li, Xiaopeng
    Niu, Rui
    Zhao, Jingxiang
    Cai, Qinghai
    CHEMICAL ENGINEERING SCIENCE, 2015, 137 : 268 - 275
  • [7] EFFICIENT CATALYTIC-OXIDATION OF CYCLIC ACETALS WITH H2O2
    ZLOTSKY, SS
    NAZAROV, MN
    KULAK, LG
    RAKHMANKULOV, DL
    JOURNAL FUR PRAKTISCHE CHEMIE-CHEMIKER-ZEITUNG, 1992, 334 (05): : 441 - 443
  • [8] Peroxotungstates immobilized on multilayer ionic liquid brushes-modified silica as an efficient and reusable catalyst for selective oxidation of sulfides with H2O2
    Shi, Xianying
    Han, Xiaoyan
    Ma, Wenjuan
    Wei, Junfa
    Li, Jing
    Zhang, Qiang
    Chen, Zhanguo
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2011, 341 (1-2) : 57 - 62
  • [9] A dicationic ionic liquid-modified phosphotungstate hybrid catalyst for the heterogeneous oxidation of alcohols with H2O2
    Leng Yan
    Zhao PingPing
    Zhang MingJue
    Chen GuoJian
    Wang Jun
    SCIENCE CHINA-CHEMISTRY, 2012, 55 (09) : 1796 - 1801
  • [10] Formation of a catalytically active intermediate for oxidation in H2O2/ionic liquid system: experimental and theoretical investigations
    Heshmatollah Alinezhad
    Majid Vafaeezadeh
    Mohammad Mahmoodi Hashemi
    Research on Chemical Intermediates, 2017, 43 : 2615 - 2625