Photocatalyst-Incorporated Cross-Linked Porous Polymer Networks

被引:10
作者
Esen, Cansu [2 ]
Kumru, Baris [1 ]
机构
[1] Delft Univ Technol, Fac Aerosp Engn, Aerosp Struct & Mat Dept, 2629 HS Delft, Netherlands
[2] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14476 Potsdam, Germany
关键词
COMPOSITE HYDROGEL; POLYDIMETHYLSILOXANE SPONGE; CHARGE SEPARATION; DEGRADATION; WATER; FILMS; TIO2; DYE; ADSORPTION; CATALYSIS;
D O I
10.1021/acs.iecr.2c01658
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The utilization of sunlight to conduct chemistry has been on a stark rise in the era of sustainability. A similar trend is observed in polymer science, mainly to initiate polymerization and modify polymer materials, but mostly relying on the utilization of soluble initiator/activator molecules. Semiconductors, on the other hand, grant a platform for "photoredox" induced chemical pathways, so that reductive and oxidative reactions (as well as radical formation) can be tailored according to band positions. Despite their utilization as dispersed or dissolved phases, immobilization of semiconductors on macroscale solid surfaces is attractive to entail scale-up options. In this Review, semiconductors incorporated in cross-linked porous polymer networks will be summarized both from synthesis and application perspectives.
引用
收藏
页码:10616 / 10630
页数:15
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