Palladium-catalysed cyclocarbonylation reactions in dimethyl carbonate, an eco-friendly solvent and ring-opening reagent

被引：33
作者：
Vasapollo, G [1 ]
Mele, G [1 ]
Maffei, A [1 ]
Del Sole, R [1 ]
机构：
[1] Univ Lecce, Dipartimento Ingn Innovaz, I-73100 Lecce, Italy
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2003年 / 17卷 / 11期
关键词：
2-allyl phenols; allyl naphthols; cyclocarbonylation; lactones; palladium; dimethyl carbonate;
D O I：
10.1002/aoc.543
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Dimethyl carbonate (DMC) is used as an alternative and eco-friendly solvent for selective cyclocarbonylation reactions of allyl phenol derivatives for the synthesis of lactones; in some cases, depending on the reaction condition, DMC behaves as a ring-opening reagent producing methoxycarbonyl compounds. Copyright (C) 2003 John Wiley Sons, Ltd.
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页码：835 / 839
页数：5
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