New coordination polymer based on a triply bridged dicarboxylate ligand:: Synthesis, structure, and magnetic properties of the adipato complex [Cu4(bpy)4(adip)3](tcnoet)2 • 2H2O {bpy=C10H8N2; adip2- = [O2C(CH2)4CO2]2-; tcnoet- = [(NC)2CC(OEt)C(CN)2]-1}

被引：19
作者：
Setifi, Fatima
Benmansour, Sarnia
Triki, Smail
Gomez-Garcia, Carlos J.
Marchivie, Mathieu
Salauen, Jean-Yves
Mustapha, Maamache
机构：
[1] Univ Bretagne Occidentale, UMR CNRS 6521, F-29285 Brest, France
[2] Univ Valencia, Inst Ciencia Mol, Valencia 46071, Spain
[3] Univ Ferhat Abbas Setif, Fac Sci, Dept Chim, Setif, Algeria
来源：
INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 13期
关键词：
copper complexes; polynitrile; adipato complexes; ladder-like structure; magnetic properties;
D O I：
10.1016/j.ica.2007.03.005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new compound of formula [Fe(qsal)(2)][Ni(dmit)(2)] (1) has been synthesised, structurally and magnetically characterised (qsalH = N(8-quinolyl)salicylaldimine, dmit(2-) = 1,3-dithiol-2-thione-4,5-dithiolato). Its structural features and its magnetic behaviour were compared with those of [Fe(qsal)(2)]-based complexes, and more particularly [Fe(qsal)(2)][Ni(dmit)(2)] center dot 2CH(3)CN. (c) 2007 Elsevier B.V. All rights reserved.
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收藏
页码：3879 / 3886
页数：8
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