BaZr0.8Y0.2O3-δ electrolyte with and without ZnO sintering aid: Preparation and characterization

被引:74
作者
Peng, Cheng [1 ]
Melnik, Juri [1 ]
Luo, Jing-Li [1 ]
Sanger, Alan R. [1 ]
Chuang, Karl T. [1 ]
机构
[1] Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 2G6, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
Yttrium-doped barium zirconate; Proton conductor; Thin-film electrolytes; Sintering; Solid oxide fuel cells; PROTON-CONDUCTING CERAMICS; ELECTRICAL-CONDUCTIVITY; CHEMICAL-STABILITY; TEMPERATURE; BAZRO3; PEROVSKITES; TRANSPORT; OXIDE; ZR;
D O I
10.1016/j.ssi.2010.07.026
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The structure, morphology and electrical conductivity for BaZr0.8Y0.2O3-delta (BZY20) and BZY20 with ZnO sintering aid are compared. Both materials have a very dense structure. The bulk and total conductivities for BZY20 with ZnO sintering aid are lower than those of BZY20 in the range 400 to 650 degrees C. Both materials are stable up to 650 degrees C in hydrogen containing 5000 ppm H2S. Dense anode-supported electrolyte thin films are prepared using spin coating. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1372 / 1377
页数:6
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