BaZr0.8Y0.2O3-δ electrolyte with and without ZnO sintering aid: Preparation and characterization

被引:70
|
作者
Peng, Cheng [1 ]
Melnik, Juri [1 ]
Luo, Jing-Li [1 ]
Sanger, Alan R. [1 ]
Chuang, Karl T. [1 ]
机构
[1] Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 2G6, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
Yttrium-doped barium zirconate; Proton conductor; Thin-film electrolytes; Sintering; Solid oxide fuel cells; PROTON-CONDUCTING CERAMICS; ELECTRICAL-CONDUCTIVITY; CHEMICAL-STABILITY; TEMPERATURE; BAZRO3; PEROVSKITES; TRANSPORT; OXIDE; ZR;
D O I
10.1016/j.ssi.2010.07.026
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The structure, morphology and electrical conductivity for BaZr0.8Y0.2O3-delta (BZY20) and BZY20 with ZnO sintering aid are compared. Both materials have a very dense structure. The bulk and total conductivities for BZY20 with ZnO sintering aid are lower than those of BZY20 in the range 400 to 650 degrees C. Both materials are stable up to 650 degrees C in hydrogen containing 5000 ppm H2S. Dense anode-supported electrolyte thin films are prepared using spin coating. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1372 / 1377
页数:6
相关论文
共 50 条
  • [1] Comparative Study on Preparation and Properties of BaZr0.8Y0.2O3-δ Solid Electrolyte
    Peng, Cheng
    Huang, Tingting
    Zheng, Yixiong
    TESTING AND EVALUATION OF INORGANIC MATERIALS IV, 2014, 591 : 240 - 244
  • [2] Reactive sintering of yttrium-doped barium zirconate (BaZr0.8Y0.2O3-δ) without sintering aids
    Goulart, Celso Antonio
    Villas Boas, Lucia Adriana
    Morelli, Marcio Raymundo
    Ferreira de Souza, Dulcina Pinatti
    CERAMICS INTERNATIONAL, 2021, 47 (02) : 2565 - 2571
  • [3] Characterization of BaZr0.8Y0.2O3-δ proton-conducting electrolyte material synthesized by pulsed-current activated sintering
    Yoo, Jong-Yeol
    Shon, In-Jin
    Choi, Byung-Hyun
    Lee, Ki-Tae
    JOURNAL OF CERAMIC PROCESSING RESEARCH, 2011, 12 (04): : 382 - 386
  • [4] Two-Step Reactive Aid Sintering of BaZr0.8Y0.2O3-δ Proton-Conducting Ceramics
    Wang, Siwei
    Chen, Yan
    Zhang, Lingling
    Ren, Cong
    Chen, Fanglin
    Brinkman, Kyle S.
    JOURNAL OF ELECTRONIC MATERIALS, 2015, 44 (12) : 4898 - 4906
  • [5] A comparative investigation on protonic ceramic fuel cell electrolytes BaZr0.8Y0.2O3-δ and BaZr0.1Ce0.7Y0.2O3-δ with NiO as sintering aid
    Chen, Meilong
    Zhou, Mingyang
    Liu, Zhijun
    Liu, Jiang
    CERAMICS INTERNATIONAL, 2022, 48 (12) : 17208 - 17216
  • [6] Moderate temperature sintering of BaZr0.8Y0.2O3-δ protonic ceramics by A novel cold sintering pretreatment
    Zhao, Zeyu
    Gao, Jun
    Meng, Yuqing
    Brinkman, Kyle S.
    Tong, Jianhua
    CERAMICS INTERNATIONAL, 2021, 47 (08) : 11313 - 11319
  • [7] Effect of NiO sintering-aid on hydration kinetics and defect-chemical parameters of BaZr0.8Y0.2O3- Δ
    Kim, E.
    Yamazaki, Y.
    Haile, S. M.
    Yoo, H. -I.
    SOLID STATE IONICS, 2015, 275 : 23 - 28
  • [8] Improvement of sinterability of BaZr0.8Y0.2O3-δ for H2 separation using Li2O/ZnO dual-sintering aid
    Li, Yuehua
    Yang, Wenjie
    Wang, Ling
    Zhu, Jing
    Meng, Wei
    He, Zhangxing
    Dai, Lei
    CERAMICS INTERNATIONAL, 2018, 44 (13) : 15935 - 15943
  • [9] Cold sintering of BaZr0.8Y0.2O3-δ ceramics: Phase formation and grain boundary properties
    Kindelmann, Moritz
    Ebert, Julian N.
    Jennings, Dylan
    Sebold, Doris
    Rheinheimer, Wolfgang
    Bram, Martin
    Mayer, Joachim
    Guillon, Olivier
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2024, 44 (05) : 2744 - 2753
  • [10] Influence of ZnO addition on microstructure and proton electrical conductivity of BaZr0.8Y0.2O3-δ ceramics
    Wendler, Leonardo P.
    Ramos, Kethlinn
    Souza, Dulcina M. P. F.
    PROCESSING AND APPLICATION OF CERAMICS, 2021, 15 (02) : 202 - 209