Lithium Sulfide as Cathode Materials for Lithium-Ion Batteries: Advances and Challenges

被引：12
作者：
Zhou, Luoting [1 ,2 ]
Zhang, Wenkui [1 ]
Wang, Yangfeng [1 ]
Liang, Sheng [3 ]
Gan, Yongping [1 ]
Huang, Hui [1 ]
Zhang, Jun [1 ]
Xia, Yang [1 ]
Liang, Chu [1 ]
机构：
[1] Zhejiang Univ Technol, Coll Mat Sci & Engn, Hangzhou 310014, Peoples R China
[2] Shaoxing Univ, Key Lab Clean Dyeing & Finishing Technol Zhejiang, Sch Text & Apparel, Shaoxing 312000, Peoples R China
[3] Hefei Univ, Sch Energy Mat & Chem Engn, Hefei 230601, Peoples R China
来源：
JOURNAL OF CHEMISTRY | 2020年 / 2020卷
基金：
中国国家自然科学基金;
关键词：
HIERARCHICAL POROUS CARBON; REDUCED GRAPHENE OXIDE; NITROGEN-DOPED CARBON; SULFUR BATTERY; HIGH-CAPACITY; LI2S-AT-C COMPOSITE; FACILE SYNTHESIS; LOW-TEMPERATURE; LI2S; PERFORMANCE;
D O I：
10.1155/2020/6904517
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Due to the ever-growing demand for high-density energy storage devices, lithium-ion batteries with a high-capacity cathode and anode are thought to be the next-generation batteries for their high energy density. Lithium sulfide (Li2S) is considered the promising cathode material for its high theoretical capacity, high melting point, affordable volume expansion, and lithium composition. This review summarizes the activation and lithium storage mechanism of Li2S cathodes. The design strategies in improving the electrochemical performance are highlighted. The application of the Li2S cathode in full cells of lithium-ion batteries is discussed. The challenges and new directions in commercial applications of Li2S cathodes are also pointed out.
引用
收藏
页数：17
相关论文
共 79 条
  • [1] A Lithium-Ion Sulfur Battery Based on a Carbon-Coated Lithium-Sulfide Cathode and an Electrodeposited Silicon-Based Anode
    Agostini, Marco
    Hassoun, Jusef
    Liu, Jun
    Jeong, Moongook
    Nara, Hiroki
    Momma, Toshiyuki
    Osaka, Tetsuya
    Sun, Yang-Kook
    Scrosati, Bruno
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (14) : 10924 - 10928
  • [2] Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/nmat3191, 10.1038/NMAT3191]
  • [3] Nanostructured Li2S-C Composites as Cathode Material for High-Energy Lithium/Sulfur Batteries
    Cai, Kunpeng
    Song, Min-Kyu
    Cairns, Elton J.
    Zhang, Yuegang
    [J]. NANO LETTERS, 2012, 12 (12) : 6474 - 6479
  • [4] Sandwich-type functionalized graphene sheet-sulfur nanocomposite for rechargeable lithium batteries
    Cao, Yuliang
    Li, Xiaolin
    Aksay, Ilhan A.
    Lemmon, John
    Nie, Zimin
    Yang, Zhenguo
    Liu, Jun
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (17) : 7660 - 7665
  • [5] Li2S encapsulated by nitrogen-doped carbon for lithium sulfur batteries
    Chen, Lin
    Liu, Yuzi
    Ashuri, Maziar
    Liu, Caihong
    Shaw, Leon L.
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (42) : 18026 - 18032
  • [6] A high-performance Li2S/MnO2 rechargeable battery
    Chen, Yan
    Lu, Songtao
    Li, Yang
    Qin, Wei
    Wu, Xiaohong
    [J]. MATERIALS LETTERS, 2019, 248 : 157 - 160
  • [7] 3D graphene framework supported Li2S coated with ultra-thin Al2O3 films: binder-free cathodes for high-performance lithium sulfur batteries
    Chen, Yan
    Lu, Songtao
    Zhou, Jia
    Wu, Xiaohong
    Qin, Wei
    Ogoke, Ogechi
    Wu, Gang
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (01) : 102 - 112
  • [8] More Reliable Lithium-Sulfur Batteries: Status, Solutions and Prospects
    Fang, Ruopian
    Zhao, Shiyong
    Sun, Zhenhua
    Wang, Wei
    Cheng, Hui-Ming
    Li, Feng
    [J]. ADVANCED MATERIALS, 2017, 29 (48)
  • [9] In Situ-Formed Li2S in Lithiated Graphite Electrodes for Lithium-Sulfur Batteries
    Fu, Yongzhu
    Zu, Chenxi
    Manthiram, Arumugam
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (48) : 18044 - 18047
  • [10] Orthorhombic Bipyramidal Sulfur Coated with Polypyrrole Nanolayers As a Cathode Material for Lithium-Sulfur Batteries
    Fu, Yongzhu
    Manthiram, Arumugam
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (16) : 8910 - 8915
12345678