Lithium Sulfide as Cathode Materials for Lithium-Ion Batteries: Advances and Challenges

被引：15

作者：

Zhou, Luoting ^{[1
,2
]}

Zhang, Wenkui ^{[1
]}

Wang, Yangfeng ^{[1
]}

Liang, Sheng ^{[3
]}

Gan, Yongping ^{[1
]}

Huang, Hui ^{[1
]}

Zhang, Jun ^{[1
]}

Xia, Yang ^{[1
]}

Liang, Chu ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Coll Mat Sci & Engn, Hangzhou 310014, Peoples R China

[2] Shaoxing Univ, Key Lab Clean Dyeing & Finishing Technol Zhejiang, Sch Text & Apparel, Shaoxing 312000, Peoples R China

[3] Hefei Univ, Sch Energy Mat & Chem Engn, Hefei 230601, Peoples R China

来源：

JOURNAL OF CHEMISTRY | 2020年 / 2020卷

基金：

中国国家自然科学基金;

关键词：

HIERARCHICAL POROUS CARBON; REDUCED GRAPHENE OXIDE; NITROGEN-DOPED CARBON; SULFUR BATTERY; HIGH-CAPACITY; LI2S-AT-C COMPOSITE; FACILE SYNTHESIS; LOW-TEMPERATURE; LI2S; PERFORMANCE;

D O I：

10.1155/2020/6904517

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Due to the ever-growing demand for high-density energy storage devices, lithium-ion batteries with a high-capacity cathode and anode are thought to be the next-generation batteries for their high energy density. Lithium sulfide (Li2S) is considered the promising cathode material for its high theoretical capacity, high melting point, affordable volume expansion, and lithium composition. This review summarizes the activation and lithium storage mechanism of Li2S cathodes. The design strategies in improving the electrochemical performance are highlighted. The application of the Li2S cathode in full cells of lithium-ion batteries is discussed. The challenges and new directions in commercial applications of Li2S cathodes are also pointed out.

引用

页数：17

共 79 条

[1] A Lithium-Ion Sulfur Battery Based on a Carbon-Coated Lithium-Sulfide Cathode and an Electrodeposited Silicon-Based Anode [J].

Agostini, Marco ;

Hassoun, Jusef ;

Liu, Jun ;

Jeong, Moongook ;

Nara, Hiroki ;

Momma, Toshiyuki ;

Osaka, Tetsuya ;

Sun, Yang-Kook ;

Scrosati, Bruno .

ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (14) :10924-10928

[2]

Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/NMAT3191, 10.1038/nmat3191]

[3] Nanostructured Li2S-C Composites as Cathode Material for High-Energy Lithium/Sulfur Batteries [J].

Cai, Kunpeng ;

Song, Min-Kyu ;

Cairns, Elton J. ;

Zhang, Yuegang .

NANO LETTERS, 2012, 12 (12) :6474-6479

[4] Sandwich-type functionalized graphene sheet-sulfur nanocomposite for rechargeable lithium batteries [J].

Cao, Yuliang ;

Li, Xiaolin ;

Aksay, Ilhan A. ;

Lemmon, John ;

Nie, Zimin ;

Yang, Zhenguo ;

Liu, Jun .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (17) :7660-7665

[5] Li2S encapsulated by nitrogen-doped carbon for lithium sulfur batteries [J].

Chen, Lin ;

Liu, Yuzi ;

Ashuri, Maziar ;

Liu, Caihong ;

Shaw, Leon L. .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (42) :18026-18032

[6] A high-performance Li2S/MnO2 rechargeable battery [J].

Chen, Yan ;

Lu, Songtao ;

Li, Yang ;

Qin, Wei ;

Wu, Xiaohong .

MATERIALS LETTERS, 2019, 248 :157-160

[7] 3D graphene framework supported Li2S coated with ultra-thin Al2O3 films: binder-free cathodes for high-performance lithium sulfur batteries [J].

Chen, Yan ;

Lu, Songtao ;

Zhou, Jia ;

Wu, Xiaohong ;

Qin, Wei ;

Ogoke, Ogechi ;

Wu, Gang .

JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (01) :102-112

[8] More Reliable Lithium-Sulfur Batteries: Status, Solutions and Prospects [J].

Fang, Ruopian ;

Zhao, Shiyong ;

Sun, Zhenhua ;

Wang, Wei ;

Cheng, Hui-Ming ;

Li, Feng .

ADVANCED MATERIALS, 2017, 29 (48)

[9] In Situ-Formed Li2S in Lithiated Graphite Electrodes for Lithium-Sulfur Batteries [J].

Fu, Yongzhu ;

Zu, Chenxi ;

Manthiram, Arumugam .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (48) :18044-18047

[10] Orthorhombic Bipyramidal Sulfur Coated with Polypyrrole Nanolayers As a Cathode Material for Lithium-Sulfur Batteries [J].

Fu, Yongzhu ;

Manthiram, Arumugam .

JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (16) :8910-8915

← 1 2 3 4 5 6 7 8 →