Hydrolytic kinetic resolution of mono- and bisepoxides as a key step in the synthesis of insect pheromones

被引：20

作者：

Chow, S ^{[1
]}

Kitching, W ^{[1
]}

机构：

[1] Univ Queensland, Dept Chem, Brisbane, Qld 4072, Australia

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 11期

关键词：

D O I：

10.1039/b102181h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthetic utility of the readily separated epoxides, diols, epoxydiols and tetrols of high enantiomeric excesses, obtained by hydrolytic kinetic resolution (HKR) of functionalised mono- and bisepoxides with (salen)Co(OAc) complexes, is demonstrated by their efficient transformations to important insect pheromones.

引用

页码：1040 / 1041

页数：2

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