Electroreduction of oxygen and carbon and single wall carbon electrooxidation of methanol at nanotube supported platinum electrodes

被引：13

作者：

Golikand, Ahmad Nozad ^{[1
]}

Irannejad, Leila ^{[1
]}

机构：

[1] NSTRI, Nucl Sci Sch, Jaber Ibne Hayyan Res Labs, Tehran, Iran

来源：

ELECTROANALYSIS | 2008年 / 20卷 / 10期

关键词：

Pt; oxygen reduction reaction; methanol oxidation; single wall carbon nanotubes;

D O I：

10.1002/elan.200704161

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The present research aimed at investigating the electrocatalytic properties and the electrochemical deposition of Pt nanoparticles on carbon powder, carbon nanotube and preparation of carbon and single wall carbon nanotube supported platinum electrodes. The Pt nanoparticles were synthesized by electroreduction of hexachloroplatinic acid in aqueous solution at -200 mV Electrocatalytic properties of the modified electrodes for oxygen reduction were investigated by cyclic voltammetry in O-2 saturated solution containing 0.1 M HClO4. Methanol electrooxidation at the modified surfaces in 0.5 M HCLO4 was studied by cyclic voltammetry. The corresponding results showed that the Pt/SWCNT/GC electrode exhibits more improved catalytical activity than the Pt/C/GC electrode.

引用

页码：1121 / 1127

页数：7

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