N-Tosylhydrazones: versatile reagents for metal-catalyzed and metal-free cross-coupling reactions

被引：566
|
作者：
Shao, Zhihui [1 ,2 ,3 ]
Zhang, Hongbin [3 ]
机构：
[1] Yunnan Univ Nationalities, Key Lab Ethn Med Resource Chem, State Ethn Affairs Commiss, Kunming 650031, Yunnan, Peoples R China
[2] Yunnan Nationalities Univ, Minist Educ, Kunming 650031, Yunnan, Peoples R China
[3] Yunnan Univ, Key Lab Med Chem Nat Resource, Sch Chem Sci & Technol, Minist Educ, Kunming 650091, Yunnan, Peoples R China
来源：
CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 02期
基金：
中国国家自然科学基金;
关键词：
ALPHA-DIAZOCARBONYL COMPOUNDS; ARYL HALIDES SYNTHESIS; CARBENE INSERTION; STEREOSELECTIVE-SYNTHESIS; CARBONYL-COMPOUNDS; ARYLBORONIC ACIDS; BENZYL BROMIDES; BORONIC ACIDS; VINYL HALIDES; DIAZOESTERS;
D O I：
10.1039/c1cs15127d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Transition metal-catalyzed cross-coupling reactions have been established as one of the most powerful tools for the construction of C-C and C-X bonds. In this context, the development of novel metal-catalyzed cross-coupling processes that do not require stoichiometric organometallic reagents is particularly attractive. Recently, N-tosylhydrazones have emerged as a new type of versatile coupling partners for transition metal-catalyzed cross-coupling reactions as well as metal-free cross-coupling reactions, and have attracted increasing attention. This tutorial review summarizes recent important developments in this area with N-tosylhydrazones as versatile coupling partners.
引用
收藏
页码：560 / 572
页数：13
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