N-Tosylhydrazones: versatile reagents for metal-catalyzed and metal-free cross-coupling reactions

被引：571

作者：

Shao, Zhihui ^{[1
,2
,3
]}

Zhang, Hongbin ^{[3
]}

机构：

[1] Yunnan Univ Nationalities, Key Lab Ethn Med Resource Chem, State Ethn Affairs Commiss, Kunming 650031, Yunnan, Peoples R China

[2] Yunnan Nationalities Univ, Minist Educ, Kunming 650031, Yunnan, Peoples R China

[3] Yunnan Univ, Key Lab Med Chem Nat Resource, Sch Chem Sci & Technol, Minist Educ, Kunming 650091, Yunnan, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 02期

基金：

中国国家自然科学基金;

关键词：

ALPHA-DIAZOCARBONYL COMPOUNDS; ARYL HALIDES SYNTHESIS; CARBENE INSERTION; STEREOSELECTIVE-SYNTHESIS; CARBONYL-COMPOUNDS; ARYLBORONIC ACIDS; BENZYL BROMIDES; BORONIC ACIDS; VINYL HALIDES; DIAZOESTERS;

D O I：

10.1039/c1cs15127d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transition metal-catalyzed cross-coupling reactions have been established as one of the most powerful tools for the construction of C-C and C-X bonds. In this context, the development of novel metal-catalyzed cross-coupling processes that do not require stoichiometric organometallic reagents is particularly attractive. Recently, N-tosylhydrazones have emerged as a new type of versatile coupling partners for transition metal-catalyzed cross-coupling reactions as well as metal-free cross-coupling reactions, and have attracted increasing attention. This tutorial review summarizes recent important developments in this area with N-tosylhydrazones as versatile coupling partners.

引用

页码：560 / 572

页数：13

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