The role of the dynamic crossover temperature and the arrest in glass-forming fluids

被引:37
|
作者
Mallamace, F. [1 ,2 ,3 ,4 ,5 ]
Corsaro, C. [4 ,5 ,6 ]
Stanley, H. E. [2 ,3 ]
Chen, S. -H. [1 ]
机构
[1] MIT, Dept Nucl Sci & Engn, Cambridge, MA 02139 USA
[2] Boston Univ, Ctr Polymer Studies, Boston, MA 02215 USA
[3] Boston Univ, Dept Phys, Boston, MA 02215 USA
[4] Univ Messina, Dipartimento Fis, I-98166 Messina, Italy
[5] Univ Messina, CNISM, I-98166 Messina, Italy
[6] Fdn Fulvio Frisone, Catania, Italy
基金
美国国家科学基金会;
关键词
STOKES-EINSTEIN RELATION; NUCLEAR-MAGNETIC-RESONANCE; SUPERCOOLED O-TERPHENYL; MODE-COUPLING THEORY; TRANSITION TEMPERATURE; CONFINED WATER; LIQUIDS; RELAXATION; VISCOSITY; BREAKDOWN;
D O I
10.1140/epje/i2011-11094-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We discuss the role of the dynamic glass-forming fragile-to-strong crossover (FSC) in supercooled liquids. In the FSC, significant dynamic changes such as the decoupling (the violation of the Stokes-Einstein relation) of homologous transport parameters, e. g., the density relaxation time tau and the viscosity eta, occur at a characteristic temperature T-c. We study the FSC using a scaling law approach. In particular, we use both forms of the mode-coupling theory (MCT): the original (ideal) and the extended form, which explicitly describes energy hopping processes. We demonstrate that T-c plays the most important physical role in understanding dynamic arrest processes.
引用
收藏
页数:12
相关论文
共 50 条
  • [21] Are polymers standard glass-forming systems? The role of intramolecular barriers on the glass-transition phenomena of glass-forming polymers
    Colmenero, J.
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2015, 27 (10)
  • [22] Arrhenius Crossover Phenomena and Ionic Conductivity in Ionic Glass-Forming Liquids
    Aniya, Masaru
    Ikeda, Masahiro
    PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2020, 257 (11):
  • [23] Manifestation of Dynamic Anomaly in Metallic Glass-Forming Liquids by Their Crystallization Processes
    Ren, Nannan
    Zhou, Chao
    Hu, Lina
    Zhou, Fan
    Tang, Jilin
    Song, Xiaokun
    Liu, Yining
    Zang, Yijing
    Chen, Yuzhong
    ADVANCED FUNCTIONAL MATERIALS (CMC 2017), 2018, : 239 - 251
  • [24] Simple Model for Dynamic Heterogeneity in Glass-Forming Liquids
    Pandit, Rajib K.
    Castillo, Horacio E.
    PHYSICAL REVIEW LETTERS, 2023, 131 (21)
  • [25] Spatial correlation of the dynamic propensity of a glass-forming liquid
    Razul, M. Shajahan G.
    Matharoo, Gurpreet S.
    Poole, Peter H.
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2011, 23 (23)
  • [26] Elasticity, Facilitation, and Dynamic Heterogeneity in Glass-Forming Liquids
    Ozawa, Misaki
    Biroli, Giulio
    PHYSICAL REVIEW LETTERS, 2023, 130 (13)
  • [27] Dynamic mechanical analysis of confined glass-forming liquids
    Koppensteiner, J.
    Schranz, W.
    PHASE TRANSITIONS, 2010, 83 (09) : 744 - 757
  • [28] The dynamic bulk modulus of three glass-forming liquids
    Gundermann, Ditte
    Niss, Kristine
    Christensen, Tage
    Dyre, Jeppe C.
    Hecksher, Tina
    JOURNAL OF CHEMICAL PHYSICS, 2014, 140 (24)
  • [29] Fragility and temperature dependence of stretched exponential relaxation in glass-forming systems
    Wilkinson, Collin J.
    Doss, Karan
    Gulbiten, Ozgur
    Allan, Douglas C.
    Mauro, John C.
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2021, 104 (09) : 4559 - 4567
  • [30] Temperature Dependence of the Viscosity of Chalcogenide Glass-Forming Melts
    A. S. Tverjanovich
    Glass Physics and Chemistry, 2003, 29 : 532 - 536