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The role of the dynamic crossover temperature and the arrest in glass-forming fluids
被引:37
|作者:
Mallamace, F.
[1
,2
,3
,4
,5
]
Corsaro, C.
[4
,5
,6
]
Stanley, H. E.
[2
,3
]
Chen, S. -H.
[1
]
机构:
[1] MIT, Dept Nucl Sci & Engn, Cambridge, MA 02139 USA
[2] Boston Univ, Ctr Polymer Studies, Boston, MA 02215 USA
[3] Boston Univ, Dept Phys, Boston, MA 02215 USA
[4] Univ Messina, Dipartimento Fis, I-98166 Messina, Italy
[5] Univ Messina, CNISM, I-98166 Messina, Italy
[6] Fdn Fulvio Frisone, Catania, Italy
基金:
美国国家科学基金会;
关键词:
STOKES-EINSTEIN RELATION;
NUCLEAR-MAGNETIC-RESONANCE;
SUPERCOOLED O-TERPHENYL;
MODE-COUPLING THEORY;
TRANSITION TEMPERATURE;
CONFINED WATER;
LIQUIDS;
RELAXATION;
VISCOSITY;
BREAKDOWN;
D O I:
10.1140/epje/i2011-11094-7
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
We discuss the role of the dynamic glass-forming fragile-to-strong crossover (FSC) in supercooled liquids. In the FSC, significant dynamic changes such as the decoupling (the violation of the Stokes-Einstein relation) of homologous transport parameters, e. g., the density relaxation time tau and the viscosity eta, occur at a characteristic temperature T-c. We study the FSC using a scaling law approach. In particular, we use both forms of the mode-coupling theory (MCT): the original (ideal) and the extended form, which explicitly describes energy hopping processes. We demonstrate that T-c plays the most important physical role in understanding dynamic arrest processes.
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页数:12
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