The role of the dynamic crossover temperature and the arrest in glass-forming fluids

被引:37
|
作者
Mallamace, F. [1 ,2 ,3 ,4 ,5 ]
Corsaro, C. [4 ,5 ,6 ]
Stanley, H. E. [2 ,3 ]
Chen, S. -H. [1 ]
机构
[1] MIT, Dept Nucl Sci & Engn, Cambridge, MA 02139 USA
[2] Boston Univ, Ctr Polymer Studies, Boston, MA 02215 USA
[3] Boston Univ, Dept Phys, Boston, MA 02215 USA
[4] Univ Messina, Dipartimento Fis, I-98166 Messina, Italy
[5] Univ Messina, CNISM, I-98166 Messina, Italy
[6] Fdn Fulvio Frisone, Catania, Italy
基金
美国国家科学基金会;
关键词
STOKES-EINSTEIN RELATION; NUCLEAR-MAGNETIC-RESONANCE; SUPERCOOLED O-TERPHENYL; MODE-COUPLING THEORY; TRANSITION TEMPERATURE; CONFINED WATER; LIQUIDS; RELAXATION; VISCOSITY; BREAKDOWN;
D O I
10.1140/epje/i2011-11094-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We discuss the role of the dynamic glass-forming fragile-to-strong crossover (FSC) in supercooled liquids. In the FSC, significant dynamic changes such as the decoupling (the violation of the Stokes-Einstein relation) of homologous transport parameters, e. g., the density relaxation time tau and the viscosity eta, occur at a characteristic temperature T-c. We study the FSC using a scaling law approach. In particular, we use both forms of the mode-coupling theory (MCT): the original (ideal) and the extended form, which explicitly describes energy hopping processes. We demonstrate that T-c plays the most important physical role in understanding dynamic arrest processes.
引用
收藏
页数:12
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