Recent progress in enantioselective synthesis of C3-functionalized oxindoles: rare earth metals take action

被引：419

作者：

Shen, Ke ^{[1
]}

Liu, Xiaohua ^{[1
]}

Lin, Lili ^{[1
]}

Feng, Xiaoming ^{[1
]}

机构：

[1] Sichuan Univ, Key Lab Green Chem & Technol, Minist Educ, Coll Chem, Chengdu 610064, Peoples R China

来源：

CHEMICAL SCIENCE | 2012年 / 3卷 / 02期

基金：

中国国家自然科学基金;

关键词：

CATALYTIC ASYMMETRIC-SYNTHESIS; FORMAL TOTAL-SYNTHESIS; LANTHANIDE COMPLEXES; ORGANIC-SYNTHESIS; NATURAL-PRODUCTS; ALPHA-AMINATION; HYDROXYMETHYLATION; DERIVATIVES; CHEMISTRY; FLUORINATION;

D O I：

10.1039/c1sc00544h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The enantioselective synthesis of 3-functionalized oxindole derivatives has experienced an explosive development. This minireview introduces the recent application of rare earth (RE) metal complex catalysts in the synthesis of targeted frameworks. The direct addition reactions of 3-substituted oxindoles or isatins are described, together with a discussion of the catalytic mechanism and related transformations to pharmaceuticals.

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收藏

页码：327 / 334

页数：8

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