Oxidative Povarov Reaction via sp3 C-H Oxidation of N-Benzylanilines Induced by Catalytic Radical Cation Salt: Synthesis of 2,4-Diarylquinoline Derivatives

被引：88

作者：

Liu, Jing

Liu, Fang

Zhu, Yingzu

Ma, Xingge

Jia, Xiaodong ^{[1
]}

机构：

[1] Northwest Normal Univ, Minist Educ, Key Lab Ecoenvironm Related Polymer Mat, Lanzhou 730070, Gansu, Peoples R China

来源：

ORGANIC LETTERS | 2015年 / 17卷 / 06期

关键词：

DIELS-ALDER REACTION; DEHYDROGENATIVE COUPLING REACTION; TERTIARY-AMINES; FACILE SYNTHESIS; BONDS; CONSTRUCTION; FUNCTIONALIZATION;

D O I：

10.1021/acs.orglett.5b00244

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidative Povarov reaction of N-benzylanilines was realized under catalytic radical cation salt induced conditions. The mechanism studies revealed that a radical intermediate was involved in this catalytic oxidation. This method provides a new way to synthesize 2,4-diarylquinoline derivatives.

引用

页码：1409 / 1412

页数：4

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