Crystal field analysis of the ground and excited state absorption of a Cr4+ ion in LiAlO2 and LiGaO2 crystals

被引：8

作者：

Brik, MG

Avram, NM

Avram, CN

机构：

[1] Kyoto Univ, Fukui Inst Fundamental Chem, Sakyo Ku, Kyoto 6068103, Japan

[2] Kwansei Gakuin Univ, Sch Sci & Technol, Sanda, Hyogo 6691337, Japan

[3] W Univ Timisoara, Dept Phys, Timisoara 300223, Romania

来源：

CENTRAL EUROPEAN JOURNAL OF PHYSICS | 2005年 / 3卷 / 04期

关键词：

crystal field theory; 3d-ions; ground and excited state absorption;

D O I：

10.2478/BF02475609

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The exchange charge model of crystal field theory has been used to analyze the ground and excited state absorption of tetrahedrally coordinated Cr4+ ion in lithium aluminum oxide LiAlO2 (gamma-phase) and lithium dioxogallate LiGaO2. The parameters of the crystal field acting on the Cr4+ ion are calculated from the crystal structure data, taking into account the crystal lattice ions located at distances up to 12.744 angstrom in LiGaO2 and 13.180 angstrom in LiAlO2. The obtained energy level schemes were compared with experimental ground and excited state absorption spectra and literature data on the application of other crystal field models (the angular overlap model and Racah theory) to the considered crystals; a good agreement with experimental data is demonstrated. (C) Central European Science Journals. All rights reserved.

引用

页码：508 / 524

页数：17

共 36 条

[31] High-resolution infrared absorption spectra, crystal-field levels, and relaxation processes in CsCdBr3:Pr3+ -: art. no. 075103 [J].