Assembly of 1,2,3,4-Benzenetetracarboxylic Acid and Zinc(II) Metal Centers to a Chiral 3D Metal-organic Framework: Syntheses, Structure and Properties

被引：3
作者：
Ji, Can [1 ]
Zang, Shuang-Quan [1 ]
Liu, Jun-Yi [1 ]
Li, Jia-Bin [1 ]
Hou, Hong-Wei [1 ]
机构：
[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450001, Peoples R China
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2011年 / 66卷 / 05期
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
Homochiral; Helical; Metal-organic Framework; Topology; SHG; Photoluminescence; HYDROGEN STORAGE; CRYSTAL-STRUCTURES; LIGAND DESIGN; ADSORPTION; ARCHITECTURES; COPPER(II); PILLAR;
D O I：
10.5560/ZNB.2011.66b0533
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new three-dimensional metal-organic framework {[Zn(mpda)(0.5)(bix)]center dot(H2O)(1.5)}(n) (1) (H(4)mpda = 1,2,3,4-benzenetetracarboxylic acid, m-bix = 1,3-bis(imidazol-1-ylmethyl)-benzene) has been synthesized and characterized by single-crystal X-ray diffraction and IR spectra. In 1, homochiral helical chains are formed in the Zn-mpda layer through spontaneous resolution by mpda(4-). Such layers are further connected through the second m-bix ligand to form a 3D chiral metal-organic framework. The individual (4,4)-connected net in 1 can be specified by the Schlafli symbol (6(6))(2)(6(4).8(2)). Bulk material of 1 has good second-harmonic generation (SHG) activity, approximately 0.4 times that of urea. In addition, a thermogravimetric analysis was carried out, and the photoluminescent behavior of the complex was also investigated.
引用
收藏
页码：533 / 537
页数：5
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  • [31] One dense and two open chiral metal-organic frameworks: Crystal structures and physical properties
    Zang, SQ
    Su, Y
    Li, YZ
    Zhu, HZ
    Meng, QJ
    [J]. INORGANIC CHEMISTRY, 2006, 45 (07) : 2972 - 2978
  • [32] 1D, 2D, and 3D Metal-Organic Frameworks Based on Bis(imidazole) Ligands and Polycarboxylates: Syntheses, Structures, and Photoluminescent Properties
    Zhang, Lai-Ping
    Ma, Jian-Fang
    Yang, Jin
    Liu, Ying-Ying
    Wei, Guo-Hua
    [J]. CRYSTAL GROWTH & DESIGN, 2009, 9 (11) : 4660 - 4673
  • [33] Hysteretic adsorption and desorption of hydrogen by nanoporous metal-organic frameworks
    Zhao, XB
    Xiao, B
    Fletcher, AJ
    Thomas, KM
    Bradshaw, D
    Rosseinsky, MJ
    [J]. SCIENCE, 2004, 306 (5698) : 1012 - 1015
  • [34] Metal-organic architectures of silver(I), cadmium(II), and copper(II) with a flexible tricarboxylate ligand
    Zhu, Hui-Fang
    Fan, Jian
    Okamura, Taka-aki
    Zhang, Zheng-Hua
    Liu, Guang-Xiang
    Yu, Kai-Bei
    Sun, Wei-Yin
    Ueyama, Norikazu
    [J]. INORGANIC CHEMISTRY, 2006, 45 (10) : 3941 - 3948
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