Assembly of 1,2,3,4-Benzenetetracarboxylic Acid and Zinc(II) Metal Centers to a Chiral 3D Metal-organic Framework: Syntheses, Structure and Properties

被引：3

作者：

Ji, Can ^{[1
]}

Zang, Shuang-Quan ^{[1
]}

Liu, Jun-Yi ^{[1
]}

Li, Jia-Bin ^{[1
]}

Hou, Hong-Wei ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450001, Peoples R China

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2011年 / 66卷 / 05期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

Homochiral; Helical; Metal-organic Framework; Topology; SHG; Photoluminescence; HYDROGEN STORAGE; CRYSTAL-STRUCTURES; LIGAND DESIGN; ADSORPTION; ARCHITECTURES; COPPER(II); PILLAR;

D O I：

10.5560/ZNB.2011.66b0533

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new three-dimensional metal-organic framework {[Zn(mpda)(0.5)(bix)]center dot(H2O)(1.5)}(n) (1) (H(4)mpda = 1,2,3,4-benzenetetracarboxylic acid, m-bix = 1,3-bis(imidazol-1-ylmethyl)-benzene) has been synthesized and characterized by single-crystal X-ray diffraction and IR spectra. In 1, homochiral helical chains are formed in the Zn-mpda layer through spontaneous resolution by mpda(4-). Such layers are further connected through the second m-bix ligand to form a 3D chiral metal-organic framework. The individual (4,4)-connected net in 1 can be specified by the Schlafli symbol (6(6))(2)(6(4).8(2)). Bulk material of 1 has good second-harmonic generation (SHG) activity, approximately 0.4 times that of urea. In addition, a thermogravimetric analysis was carried out, and the photoluminescent behavior of the complex was also investigated.

引用

页码：533 / 537

页数：5

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