Nanoscale Light-Harvesting Metal-Organic Frameworks

被引：139

作者：

Zhang, Xuanjun ^{[1
]}

Ballem, Mohamed Ali ^{[1
]}

Hu, Zhang-Jun ^{[1
]}

Bergman, Peder ^{[1
]}

Uvdal, Kajsa ^{[1
]}

机构：

[1] Linkoping Univ, Dept Phys Chem & Biol, S-58183 Linkoping, Sweden

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 25期

关键词：

lanthanides; light harvesting; metal-organic frameworks; nanocolloids; nanostructures; COORDINATION POLYMERS; ENERGY-TRANSFER; GIANT PORES; NANOPARTICLES; LUMINESCENCE; EFFICIENT; TEMPERATURE; NANOFIBERS; SIZE;

D O I：

10.1002/anie.201007277

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly crystalline nanoparticles of metal-organic frameworks with efficient light-harvesting properties were prepared by coordination-directed assembly (see picture). Functionalization of the ligands with long alkyl chains effectively stabilizes the nanoparticles and increases crystallinity. Different metal ions and ligands are organized into single nanoparticles and both organic acceptors and lanthanide ions can be co-sensitized within the frameworks. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5728 / 5732

页数：5

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