Effect of pH and shear force on flocs characteristics for humic acid removal using polyferric aluminum chloride-organic polymer dual-coagulants

被引:32
作者
Sun, Cuizhen [1 ,2 ]
Yue, Qinyan [1 ]
Gao, Baoyu [1 ]
Mu, Ruimin [2 ]
Liu, Jing [2 ]
Zhao, Yanxia [1 ]
Yang, Zhonglian [1 ]
Xu, Weiying [1 ]
机构
[1] Shandong Univ, Shandong Key Lab Water Pollut Control & Resource, Sch Environm Sci & Engn, Jinan 250100, Peoples R China
[2] Shandong Jianzhu Univ, Sch Municipal & Environm Engn, Jinan 250100, Peoples R China
关键词
Composite coagulant; Floc breakage; Fractal dimension; Floc regrowth; Humic acid; POLYALUMINUM CHLORIDE; FLOCCULATION; BREAKAGE; PARTICLES; REGROWTH;
D O I
10.1016/j.desal.2011.07.065
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The growth, breakage, regrowth and fractal nature of the aggregated flocs formed by a new composite coagulant, polyferric aluminum chloride-polydimethyldiallylammonium chloride, with humic acid were investigated. Different solution pH and various shear forces were investigated to evaluate the size, strength and structure of the flocs. The results showed that the flocs generated in acid conditions were more resistant to shear and more recoverable than those did in alkaline conditions, with the results suggesting that the order of the floc strength and recoverability was pH 5>pH 6>pH 8. The ability of flocs to resist breakage decreased as the shear rate increased and the reformation of flocs after high shear was limited. Fractal dimension analysis indicated that the flocs formed in acid pHs were more compact than those formed in alkaline pHs. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:243 / 247
页数:5
相关论文
共 35 条
[1]   SURFACE GEOMETRIC IRREGULARITY OF PARTICULATE MATERIALS - THE FRACTAL APPROACH [J].
AVNIR, D ;
FARIN, D ;
PFEIFER, P .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1985, 103 (01) :112-123
[2]   Activated sludge flocculation: On-line determination of floc size and the effect of shear [J].
Biggs, CA ;
Lant, PA .
WATER RESEARCH, 2000, 34 (09) :2542-2550
[3]   Particles under stress [J].
Boller, M ;
Blaser, S .
WATER SCIENCE AND TECHNOLOGY, 1998, 37 (10) :9-29
[4]   Evolution of size distribution and transfer of mineral particles between flocs in activated sludges: an insight into floc exchange dynamics [J].
Chaignon, V ;
Lartiges, BS ;
El Samrani, A ;
Mustin, C .
WATER RESEARCH, 2002, 36 (03) :676-684
[5]   IDENTITY AND YIELDS OF MAJOR HALOGENATED PRODUCTS OF AQUATIC FULVIC-ACID CHLORINATION [J].
CHRISTMAN, RF ;
NORWOOD, DL ;
MILLINGTON, DS ;
JOHNSON, JD ;
STEVENS, AA .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1983, 17 (10) :625-628
[6]  
Chu X.B., 2011, J HAZARD MATER, V187, P495
[7]  
DEMPSEY BA, 1984, J AM WATER WORKS ASS, V76, P141
[8]   Binding of organic pollutants to humic and fulvic acids: Influence of pH and the structure of humic material [J].
DePaolis, F ;
Kukkonen, J .
CHEMOSPHERE, 1997, 34 (08) :1693-1704
[9]  
Feder J., 1988, Fractals
[10]   The density of particle aggregates [J].
Gregory, J .
WATER SCIENCE AND TECHNOLOGY, 1997, 36 (04) :1-13