Four-coordinate six-membered ketiminate and diketiminate boron complexes. Synthesis, structure, reactivity, and application in the design of nitrogen heterocycles

被引：10

作者：

Vasil'ev, L. S. ^{[1
]}

Baranin, S. V. ^{[1
]}

Zavarzin, I. V. ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Prosp, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2017年 / 66卷 / 08期

关键词：

ketiminate and diketiminate boron complexes; structure; synthesis; chemical properties; synthesis of nitrogen heterocycles from ketiminate and diketiminate boron complexes; CHELATE SYNTHESIS; ORGANOBORON COMPOUNDS; FUNCTIONALIZED PYRIDINES; POTENTIAL REAGENTS; SUPPORTED BORON; DERIVATIVES; LIGANDS; ACID; DYES; TRIFLUOROACETONITRILE;

D O I：

10.1007/s11172-017-1901-x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The data on ketiminate and diketiminate boron complexes are first reviewed. The present review is focused on the synthesis and chemical transformations of these chelates. The special attention is paid to the application of these boron chelates in the synthesis of nitrogen heterocycles including CF3-substituted derivatives.

引用

页码：1398 / 1418

页数：21

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