Synthesis of Mesoporous Wall-Structured TiO2 on Reduced Graphene Oxide Nanosheets with High Rate Performance for Lithium-Ion Batteries

被引:28
作者
Zhen, Mengmeng [1 ]
Sun, Meiqing [1 ]
Gao, Guandao [1 ]
Liu, Lu [1 ]
Zhou, Zhen [2 ]
机构
[1] Nankai Univ, Coll Environm Sci & Engn, Tianjin Key Lab Environm Remediat & Pollut Contro, Tianjin 300071, Peoples R China
[2] Nankai Univ, Tianjin Key Lab Met & Mol Based Mat Chem, Key Lab Adv Energy Mat Chem,Minist Educ, Inst New Energy Mat Chem,Collaborat Innovat Ctr C, Tianjin 300071, Peoples R China
关键词
anodes; electrochemistry; Li-ion batteries; mesoporous wall; nanostructures; IN-SITU; ANODE; COMPOSITES; STORAGE; NANOCOMPOSITES; CRYSTALS; NITROGEN; ARRAYS; CARBON;
D O I
10.1002/chem.201406678
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mesoporous wall-structured TiO2 on reduced graphene oxide (RGO) nanosheets were successfully fabricated through a simple hydrothermal process without any surfactants and annealed at 400 degrees C for 2 h under argon. The obtained mesoporous structured TiO2-RGO composites had a high surface area (99 0307 m(2)g(-1)) and exhibited excellent electrochemical cycling (a reversible capacity of 260 mAh g(-1) at 1.2 C and 180 mAh g(-1) at 5 C after 400 cycles), demonstrating it to be a promising method for the development of high-performance Li-ion batteries.
引用
收藏
页码:5317 / 5322
页数:6
相关论文
共 39 条
  • [1] Design and evaluation of novel Zn doped mesoporous TiO2 based anode material for advanced lithium ion batteries
    Ali, Zahid
    Cha, Seung Nam
    Sohn, Jung Inn
    Shakir, Imran
    Yan, Changzeng
    Kim, Jong Min
    Kang, Dae Joon
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (34) : 17625 - 17629
  • [2] Evaluating the performance of nanostructured materials as lithium-ion battery electrodes
    Armstrong, Mark J.
    O'Dwyer, Colm
    Macklin, William J.
    Holmes, Justin. D.
    [J]. NANO RESEARCH, 2014, 7 (01) : 1 - 62
  • [3] Bruce P.G., 2008, Angew. Chem, V120, P2972, DOI DOI 10.1002/ANGE.200702505
  • [4] Synthesis and superior anode performance of TiO2@reduced graphene oxide nanocomposites for lithium ion batteries
    Cao, Huaqiang
    Li, Baojun
    Zhang, Jingxian
    Lian, Fang
    Kong, Xianghua
    Qu, Meizhen
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (19) : 9759 - 9766
  • [5] TiO2-B Nanosheets/Anatase Nanocrystals Co-Anchored on Nanoporous Graphene: In Situ Reduction-Hydrolysis Synthesis and Their Superior Rate Performance as an Anode Material
    Chen, Chaoji
    Hu, Xianluo
    Jiang, Yan
    Yang, Ze
    Hu, Pei
    Huang, Yunhui
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (05) : 1383 - 1388
  • [6] SnO2 hollow structures and TiO2 nanosheets for lithium-ion batteries
    Chen, Jun Song
    Archer, Lynden A.
    Lou, Xiong Wen
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (27) : 9912 - 9924
  • [7] Graphene-supported anatase TiO2 nanosheets for fast lithium storage
    Ding, Shujiang
    Chen, Jun Song
    Luan, Deyan
    Boey, Freddy Yin Chiang
    Madhavi, Srinivasan
    Lou, Xiong Wen
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (20) : 5780 - 5782
  • [8] Control of Graphene's Properties by Reversible Hydrogenation: Evidence for Graphane
    Elias, D. C.
    Nair, R. R.
    Mohiuddin, T. M. G.
    Morozov, S. V.
    Blake, P.
    Halsall, M. P.
    Ferrari, A. C.
    Boukhvalov, D. W.
    Katsnelson, M. I.
    Geim, A. K.
    Novoselov, K. S.
    [J]. SCIENCE, 2009, 323 (5914) : 610 - 613
  • [9] Chemically Bonded TiO2-Bronze Nanosheet/Reduced Graphene Oxide Hybrid for High-Power Lithium Ion Batteries
    Etacheri, Vinodkumar
    Yourey, Joseph E.
    Bartlett, Bart M.
    [J]. ACS NANO, 2014, 8 (02) : 1491 - 1499
  • [10] Growth of TiO2 nanorod arrays on reduced graphene oxide with enhanced lithium-ion storage
    He, Lifang
    Ma, Ruguang
    Du, Ning
    Ren, Jianguo
    Wong, Tailun
    Li, Yangyang
    Lee, Shuit Tong
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (36) : 19061 - 19066