Synthesis of polymer based catalyst: Optimization and kinetics modeling of the transesterification of Pistacia chinensis oil with diethyl carbonate using acidic ionic liquids

被引：32
作者：
Panchal, Balaji [1 ]
Chang, Tao [1 ]
Kang, Yanhui [1 ]
Qin, Shenjun [1 ]
Zhao, Qiaojing [1 ]
Wang, Jinxi [1 ]
Bian, Kai [1 ]
Sun, Yuzhuang [1 ]
机构：
[1] Hebei Univ Engn, Key Lab Resource Explorat Res, Handan 056038, Hebei, Peoples R China
来源：
FUEL | 2020年 / 276卷
基金：
中国国家自然科学基金; 美国国家科学基金会;
关键词：
Pistacia chinensis seed oil; Oleic acid; Solid acidic polymeric ionic liquids; Esterification; Transesterification; SUPERCRITICAL METHANOL TRANSESTERIFICATION; BIODIESEL PRODUCTION; EMISSION CHARACTERISTICS; ENGINE PERFORMANCE; SEED OIL; ESTERIFICATION; GLYCEROL; BLENDS;
D O I：
10.1016/j.fuel.2020.118121
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
A novel solid acidic polymeric ionic liquid catalyst was synthesized for ethyl esters production via the esterification of oleic acid with ethanol, normally transesterification of Pistacia chinensis oil with diethyl carbonate. Gas chromatography-mass spectroscopy analysis was used to characterize the products and optimize the reaction conditions to provide P. chinensis oil derived ethyl esters in 93% yield. Kinetic studies performed at different temperatures revealed that the conversion of P. chinensis oil to an ethyl ester follows first order reaction kinetics. The properties of ethyl esters were determined, found to meet the ASTM D6751-02. Results revealed that the catalyst had perfect utility after several runs without much loss in activity. The mild conditions (1:5) P. chinensis oil:diethyl carbonate molar ratio, 300 wt% PIL loading, 120 degrees C, 400 rpm, 6 h, recyclability of the catalyst make the proposed synthesis a sustainable method for the development of ecofriendly, cost-effective biofuels.
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页数：11
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