Visible Light-Mediated Metal-Free Decarboxylative Deuteration of Carboxylic Acid

被引：8
|
作者：
He Yuhang [1 ]
Yang Hui [1 ]
Gao Dongxu [1 ]
Ma Jiahui [1 ]
Shao Yamin [1 ]
An Guanghui [1 ]
Li Guangming [1 ]
机构：
[1] Heilongjiang Univ, Sch Chem & Mat Sci, Key Lab Funct Inorgan Mat Chem, Harbin 150080, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 41卷 / 12期
基金：
中国国家自然科学基金;
关键词：
photochemistry; metal-free; decarboxylation; deuteration; EXTERNAL PHOTOSENSITIZER-FREE; CATALYZED DEUTERATION; ARYL HALIDES; DEUTERIUM; ALCOHOLS; QUINOXALIN-2(1H)-ONES; FORMYLATION; D2O;
D O I：
10.6023/cjoc202111014
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A metal-free visible light-induced decarboxylation of phenylacetic acid derivatives has been successfully developed. Without the additives, direct decarboxylative monodeuteration of acids was successfully achieved using cheap deuterium sources. Besides, in presence of air, similar catalytic systems provided ketone products.
引用
收藏
页码：4725 / 4731
页数：7
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