Reversible conversion of valence-tautomeric copper metal-organic frameworks dependent single-crystal-to-single-crystal oxidation/reduction: a redox-switchable catalyst for C-H bonds activation reaction

被引：66

作者：

Huang, Chao ^{[1
]}

Wu, Jie ^{[1
]}

Song, Chuanjun ^{[1
]}

Ding, Ran ^{[1
]}

Qiao, Yan ^{[1
]}

Hou, Hongwei ^{[1
]}

Chang, Junbiao ^{[1
]}

Fan, Yaoting ^{[1
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 51期

基金：

中国国家自然科学基金;

关键词：

ACTIVE LIGANDS; TRANSFORMATION; NANOPARTICLES; CONDUCTIVITY; COMPLEXES; OXIDATION;

D O I：

10.1039/c5cc02432c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Upon single-crystal-to-single-crystal (SCSC) oxidation/reduction, reversible structural transformations take place between the anionic porous zeolite-like Cu-I framework and a topologically equivalent neutral (CuCuII)-Cu-I mixed-valent framework. The unique conversion behavior of the Cu-I framework endowed it as a redox-switchable catalyst for the direct arylation of heterocycle C-H bonds.

引用

页码：10353 / 10356

页数：4

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