Silyl-, germyl-, and stannyl-substituted group 6 pentacarbonyl metalates

被引：22

作者：

Wagner, H ^{[1
]}

Baumgartner, J ^{[1
]}

Marschner, C ^{[1
]}

机构：

[1] Graz Univ Technol, Inst Anorgan Chem, A-8010 Graz, Austria

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 19期

关键词：

D O I：

10.1021/om0503747

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of silylated silyl-, germyl-, and stannyl anions with group 6 halogenpentacarbonyl metalates gave the respective pentacarbonyl metalate derivatives. With the exception of a stannylated chromate all compounds were obtained in good yields and selectivity. An alternative approach employing group 6 metal hexacarbonyls in the reaction with the group 14 anions worked equally well. All compounds were fully characterized spectroscopically, and four compounds were subjected to single-crystal structure analysis.

引用

页码：4649 / 4653

页数：5

共 35 条

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