Activated Carbons for Hydrothermal Decarboxylation of Fatty Acids

被引：118

作者：

Fu, Jie ^{[1
]}

Shi, Fan ^{[1
]}

Thompson, L. T., Jr. ^{[1
]}

Lu, Xiuyang ^{[2
]}

Savage, Phillip E. ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem Engn, Ann Arbor, MI 48109 USA

[2] Zhejiang Univ, Dept Chem & Biol Engn, Hangzhou 310027, Peoples R China

来源：

ACS CATALYSIS | 2011年 / 1卷 / 03期

基金：

美国国家科学基金会;

关键词：

supercritical; kinetics; cracking; biofuel; SUPERCRITICAL WATER OXIDATION; CATALYTIC DEOXYGENATION; GASIFICATION; PHENOL; LIQUEFACTION; FEEDSTOCKS; BIODIESEL;

D O I：

10.1021/cs1001306

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

we converted palmitic and oleic acids to fuel range hydrocarbons using two activated carbons in near and supercritial water with no H-2 added. The main products from palmitic acid were C-8-C-15 n-alkenes. The major products from oleic acid were C-12-C-17 n-alkanes and some C-17 olefins. The pseudo-first-order rate constants displayed Arrhenius behavior. The apparent activation energy displayed Arrhenius behaviour The apparent activation energy of 125 kJ/mol for palmitic acid decarboxylation is higher than that observed with a 5% Pt/C catalyst. Nevertheless, these results show that activated carbons possess catalytic activity for the hydrothermal decarboxylation of fatty acids.

引用

页码：227 / 231

页数：5

共 23 条

[1] Active carbons as catalysts for liquid phase reactions [J].