Octupolar crystals for nonlinear optics: 1,3,5-trinitro-2,4,6-tris(styryl)benzene derivatives

被引：89
|
作者：
Cho, BR
Lee, SJ
Lee, SH
Son, KH
Kim, YH
Doo, JY
Lee, GJ
Kang, TI
Lee, YK
Cho, MH
Jeon, SJ
机构：
[1] Korea Univ, Dept Chem, Mol Optoelect Lab, Seoul 136701, South Korea
[2] Korea Univ, Ctr Electro & Photorespons Mol, Seoul 136701, South Korea
来源：
CHEMISTRY OF MATERIALS | 2001年 / 13卷 / 05期
关键词：
D O I：
10.1021/cm000816z
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
1,3,5-Trinitro-2,4,6-tris(styryl)benzene derivatives 1-3 were synthesized and their optical properties, first hyperpolarizabilities (beta), powder SHG efficiencies, and Td, were determined. They exhibited significant beta [beta (0) = (24-89) x 10(-30) esu] and powder SHG values [M/M-mNA = 0.2-5.8] as well as high thermal stabilities (T-d(d) = 210-310 degreesC). [GRAPHICS]
引用
收藏
页码：1438 / +
页数：4
相关论文
共 50 条
  • [41] 2,4,6-Tris(diazo)cyclohexane-1,3,5-trione
    Technische Universitaet Braunschweig, Braunschweig, Germany
    Acta Crystallogr Sect C Cryst Struct Commun, pt 6 (783-786):
  • [42] Synthesis, Crystal Structure, and Biological Activity of 1,3,5-Thimethyl-2,4,6-tris(3'-methyl-1'-imidazoliomethylene)Benzene Perchlorate
    J.-F. Lu
    C.-B. Zhao
    J. Shi
    L.-X. Jin
    G.-X. Hua
    H.-G. Ge
    Crystallography Reports, 2017, 62 : 1051 - 1054
  • [43] Synthesis, Crystal Structure, and Biological Activity of 1,3,5-Thimethyl-2,4,6-tris(3′-methyl-1′-imidazoliomethylene)Benzene Perchlorate
    Lu, J. -F.
    Zhao, C. -B.
    Shi, J.
    Jin, L. -X.
    Hua, G. -X.
    Ge, H. -G.
    CRYSTALLOGRAPHY REPORTS, 2017, 62 (07) : 1051 - 1054
  • [44] NUCLEOPHILIC-SUBSTITUTION REACTIONS OF 2,4,6-TRIS(TRINITROMETHYL)-1,3,5-TRIAZINE .2. INTERACTION OF 2,4,6-TRIS(TRINITROMETHYL)-1,3,5-TRIAZINE WITH PRIMARY AMINES AND HEXAMETHYLDISILAZANE
    SHASTIN, AV
    GODOVIKOVA, TI
    GOLOVA, SP
    POVORIN, MV
    DMITRIEV, DE
    DEKAPRILEVICH, MO
    STRELENKO, YA
    STRUCHKOV, YT
    KHMELNITSKY, LI
    KORSUNSKY, BL
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1995, (05): : 679 - 688
  • [45] ELECTRON DELOCALIZATION IN 2,4,6-TRIS(1,3-DITHIOL-2-YLIDENE)-1,3,5-CYCLOHEXANETRIONE AND 2,4,6-TRIS(1,3-DITHIOLAN-2-YLIDENE)-1,3,5-CYCLOHEXANETRIONE
    KIMURA, M
    WATSON, WH
    NAKAYAMA, J
    JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (18): : 3719 - 3721
  • [46] 1,3,5-Triferrocenyl-2,4,6-tris(ethynylferrocenyl)benzene - a new member of the family of multiferrocenyl-functionalized cyclic systems
    Pfaff, Ulrike
    Filipczyk, Grzegorz
    Hildebrandt, Alexander
    Korb, Marcus
    Lang, Heinrich
    DALTON TRANSACTIONS, 2014, 43 (43) : 16310 - 16321
  • [47] 1,3,5-tris(cyanomethyl)-2,4,6-triethyl-benzene
    Walsdorff, C
    Park, KM
    Oh, J
    Kim, K
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 108 - 110
  • [48] RING TRANSFORMATION OF 2,4,6-TRIS(AMINOALKENYL)-1,3,5-TRIAZINES TO 4-AMINOPYRIMIDINES
    SCHULZ, HJ
    LIEBSCHER, J
    MAAS, G
    LIEBIGS ANNALEN DER CHEMIE, 1992, (04): : 411 - 412
  • [49] Polymorphs of 2,4,6-tris(4-pyridyl)-1,3,5-triazine and their mechanical properties
    Yuan, Liangqian
    Xing, Mengyao
    Pan, Fangfang
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2019, 75 : 987 - 993
  • [50] ELECTRON-DIFFRACTION STUDY OF MOLECULAR-STRUCTURE OF 1,3,5-TRINITRO-2,4,6-TRICHLOROBENZENE IN GAS-PHASE
    KULIKOVA, EI
    SADOVA, NI
    VILKOV, LV
    POPIK, MV
    IVANOV, AA
    PYATAKOV, NF
    PANKRUSHEV, YA
    VESTNIK MOSKOVSKOGO UNIVERSITETA SERIYA 2 KHIMIYA, 1989, 30 (04): : 338 - 342
12345