Removal of nitrophenol pesticides from aqueous solutions by layered double hydroxides and their calcined products

被引:63
作者
Chaara, D. [1 ,2 ]
Pavlovic, I. [1 ]
Bruna, F. [1 ]
Ulibarri, M. A. [1 ]
Draoui, K. [2 ]
Barriga, C. [1 ]
机构
[1] Univ Cordoba, Dept Quim Inorgan & Ingn Quim, E-14071 Cordoba, Spain
[2] Fac Sci, Lab LPCIE, Dept Chim, Tetouan, Morocco
关键词
Hydrotalcite; Pesticide; Adsorption; Dinitrophenol; Dinitrocresol; INTERLAYER ANION; HYDROTALCITE; ADSORPTION; SORBENT; INTERCALATION; CLAYS;
D O I
10.1016/j.clay.2010.08.002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The ability of MgAl layered double hydroxides (LDHs) and their calcined products to adsorb the water contaminants 2 4-dinitrophenol (DNP) and 2-methyl-4 6-dinitrophenol (DNOC) was assessed Adsorption tests were conducted on LDHs with variable Mg/Al ratios (and variable layer charge) pH values contact times and initial pesticide concentrations to identify the optimum conditions for the intended purpose Adsorbents and adsorption products were characterized by X-ray diffraction and FT-IR spectroscopy as well as atomic absorption spectroscopy and thermal analyses The amounts of pesticides removed from water were determined by UV-Vis spectrophotometry All adsorbents except the carbonate-containing hydrotalcite possessed a very high adsorption capacity for both contaminants (C) 2010 Elsevier B V All rights reserved
引用
收藏
页码:292 / 298
页数:7
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