Synthesis of the porphyrin-calix[4]arene conjugates via Pd-catalyzed amination and their evaluation as fluorescent chemosensors

被引：4

作者：

Yakushev, Alexei A. ^{[1
]}

Averin, Alexei D. ^{[1
]}

Sakovich, Maria, V ^{[1
]}

Vatsouro, Ivan M. ^{[1
]}

Kovalev, Vladimir V. ^{[1
]}

Syrbu, Sergey A. ^{[2
]}

Koifman, Oskar, I ^{[3
]}

Beletskaya, Irina P. ^{[1
]}

机构：

[1] Lomonosov Moscow State Univ, Dept Chem, Leninskie Gory 1-3, Moscow 119991, Russia

[2] RAS, GA Krestov Inst Solut Chem, 1 Akad Skaya Ul, Ivanovo 153045, Russia

[3] Ivanovo State Univ Chem Technol, 7 Sheremetevskii Prosp, Ivanovo 153000, Russia

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2019年 / 23卷 / 11-12期

关键词：

porphyrin; calix[4]arene; Pd catalysis; amination; fluorescence; detection; CALIXARENE-PORPHYRIN CONJUGATE; ELECTRON-TRANSFER; RECEPTORS; ETHER; COMPLEXES; TWEEZERS; SENSOR; FE3+; ION; AG+;

D O I：

10.1142/S1088424619501761

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of the porphyrin-calix[4]arene conjugates was carried out using the Pd(0)-catalyzed amination of Zn(II) meso-(3-bromophenyl)porphyrinate with bis(3-aminopropoxy)substituted calix[4]arenes (in cone and 1,3-alternate conformations). One of the conjugates was demetalated to give free porphyrin base derivative. The investigation of the fluorescence of the conjugates was studied in the presence of 18 metal perchlorates. The zinc porphyrinate derivatives were found to quench fluorescence in the presence of Cu(II), Al(III) and Cr(III) cations as well as on protonation. Metal-free conjugate was shown to act as a molecular probe for Zn(II), Cu(II) and Cd(II) cations due to strong and different changes of the emission caused by these metals.

引用

页码：1551 / 1562

页数：12

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