Stereospecific Palladium-Catalyzed Decarboxylative C(sp3)-C(sp2) Coupling of 2,5-Cyclohexadiene-1-carboxylic Acid Derivatives with Aryl Iodides

被引：27
作者：
Chou, Chih-Ming [1 ]
Chatterjee, Indranil [1 ]
Studer, Armido [1 ]
机构：
[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 37期
关键词：
asymmetric synthesis; Birch reduction; C-C bond formation; homogeneous catalysis; palladium; KOCH-HAAF CARBOXYLATIONS; METALATED CYCLOHEXADIENES; REDUCTION-ALKYLATION; ALLYLIC ALKYLATION; BIRCH REDUCTION; DESYMMETRIZATION; ALLYLATION; OLEFINATION; HALIDES;
D O I：
10.1002/anie.201103450
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Walk on the same side! The title reaction occurs by means of highly stereospecific 1,3-metal migration. The starting carboxylic acids are readily prepared by Birch reduction, and the developed protocol provides an efficient route to enantiomerically pure 5-arylated-1,3-cyclohexadiene derivatives (see scheme). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页码：8614 / 8617
页数：4
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