Supramolecular metal oxides:: Programmed hierarchical assembly of a protein-sized 21 kDa [(C16H36N)19{H2NC(CH2O)3P2V3W15O59}4]5- polyoxometalate assembly

被引：160

作者：

Pradeep, Chullikkattil P. ^{[1
]}

Long, De-Liang ^{[1
]}

Newton, Graham N. ^{[1
]}

Song, Yu-Fei ^{[1
]}

Cronin, Leroy ^{[1
]}

机构：

[1] Univ Glasgow, Dept Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 23期

关键词：

hydrogen bonds; polyoxometalates; self-assembly; supramolecular chemistry; tungsten;

D O I：

10.1002/anie.200800431

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Covalent grafting of "organic caps" onto Dawson metal oxide clusters controls their supramolecular self-assembly in the solid and solution phase. Formation can be controlled by changing the solvent and the hydrogen-bonding groups on the cap. A gigantic nanoassembly with a mass of ca. 21 kDa is characterized unambiguously in the solid state using single-crystal XRD, and detected in solution/gas phase by cryospray mass spectrometry as the 5- ion. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4388 / 4391

页数：4

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